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Novel Pyridine-Catalyzed Reactionof Dimethyl Acetylenedicarboxylate with Aldehydes and N-Tosylimines: Efficient Synthesis of2-Benzoylfumarates and 1-Azadienes

Vijay Nair*a, A. R. Sreekantha, N. Abhilasha, A. T. Bijua, B. Rema Devia, Rajeev. S. Menona, Nigam P. Rathb, R. Srinivasc
a Organic Chemistry Division, Regional Research Laboratory (CSIR), Trivandrum695 019, India
Fax: +91(472)2491712; e-Mail: vijaynair_2001@yahoo.com;
b Department of Chemistry, Universityof Missouri-St. Louis, Missouri-63121-4499, USA
c National Center for Mass Spectrometry, Indian Institute of Chemical Technology (CSIR), Hyderabad 500 007, India