Direct Halo-Oxygenation of Alkenes with IBX and Potassium Halide

Zhenliang Pan; Xueyuan Liu; Weimin Liu; Yongmin Liang

doi:10.1055/s-2004-834948

PAPER

Direct Halo-Oxygenation of Alkenes with IBX and Potassium Halide

Zhenliang Pan^a, Xueyuan Liu^a, Weimin Liu^b, Yongmin Liang*^a,b
^a State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China
^b State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China
Fax: +86(931)8912582; e-Mail: liangym1@hotmail.com;

Abstract

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Abstract

The direct halo-oxygenation of alkenes by IBX in the presence of potassium halide is described, in which two issues have been approached: (a) the products are formed atom-economically with retention of the main skeleton of IBX; and (b) the products contain multi-functional groups offering further synthetic applicability.

Key words

addition - alkene - halo-oxygenation - hypervalent iodine - IBX

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