Aluminium Triflate [Al(OTf)3] as a Recyclable Catalyst for the Conversion of α-Hydroxyphosphonates, Alcohols and Phenols to Their Corresponding O-Silylated Products with Hexamethyldisilazane (HMDS)

Habib Firouzabadi; Nasser Iranpoor; Sara Sobhani; Soheila Ghassamipour

doi:10.1055/s-2005-861789

PAPER

Aluminium Triflate [Al(OTf)₃] as a Recyclable Catalyst for the Conversion of α-Hydroxyphosphonates, Alcohols and Phenols to Their Corresponding O-Silylated Products with Hexamethyldisilazane (HMDS)

Habib Firouzabadi*, Nasser Iranpoor*, Sara Sobhani, Soheila Ghassamipour
Department of Chemistry, College of Sciences, Shiraz University, Shiraz 71454, Iran
Fax: +98(711)2280926; e-Mail: Firouzabadi@chem.susc.ac.ir; e-Mail: Iranpoor@chem.susc.ac.ir;

Abstract

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Abstract

Al(OTf)₃ as a recyclable catalyst conducts the efficient conversion of various types of α-hydroxyphosphonates to their corresponding α-trimethysilyloxyphosphonates with HMDS in the absence of solvent at room temperature. The general applicability of the catalyst under solvent-free conditions is demonstrated by applying it for the successful silylation of alcohols and phenols with HMDS in high yields.

Keywords

α-hydroxyphosphonates - solvent-free - aluminium triflate - α-acetyloxyphosphonates - alcohols - phenols

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References

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