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Synthesis 2005(13): 2215-2219  
DOI: 10.1055/s-2005-872093
PAPER
© Georg Thieme Verlag Stuttgart · New York

Synthesis of Geminal Bisperoxides by Acid-Catalyzed Reaction of Acetals and Enol Ethers with tert-Butyl Hydroperoxide

Alexander O. Terent’ev*, Alexander V. Kutkin, Nikolay A. Troizky, Yuri N. Ogibin, Gennady I. Nikishin
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, 119991 Moscow, Russia
Fax: +8(095)135 5328; e-Mail: alterex@yandex.ru;
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Publication History

Received 3 March 2005
Publication Date:
22 July 2005 (online)

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Abstract

A new efficient procedure was developed for the synthesis of geminal bisperoxides by reaction of ketals and enol ethers with tert-butyl hydroperoxide catalyzed by protic or Lewis acids.

Key words

acetals - enol ethers - tert-butyl hydroperoxide - gem-bisperoxides

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