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Synthesis 2006(5): 880-884
DOI: 10.1055/s-2006-926320
DOI: 10.1055/s-2006-926320
PAPER
© Georg Thieme Verlag Stuttgart · New York
Synthesis of (±)-(2-Methylenecyclopropyl)glycine and (±)-4-[(Amino(carboxymethyl)]spiro[2.2]pentane-1-carboxylic Acid
Further Information
Received
1 September 2005
Publication Date:
07 February 2006 (online)
Publication History
Publication Date:
07 February 2006 (online)
Abstract
A facile method for the preparation of racemic cyclopropylglycines is described, involving oxidation of cyclopropylcarbinols followed by a Bucherer-Berg reaction with sequential hydrolysis of the hydantoins obtained.
Key words
[1+2] cycloaddition - Bucherer-Berg reaction - cyclopropylglycines - carbenes - diazo compounds
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