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Synthesis 2006(21): 3617-3620
DOI: 10.1055/s-2006-950189
DOI: 10.1055/s-2006-950189
PAPER
© Georg Thieme Verlag Stuttgart · New York
Facile and Selective Aerobic Oxidation of Arylalkanes to Aryl Ketones Using Cesium Carbonate
Further Information
Received
2 June 2006
Publication Date:
15 August 2006 (online)
Publication History
Publication Date:
15 August 2006 (online)
Abstract
Various arylalkanes such as fluorenes, xanthene, anthrone, 9,10-dihydroanthracene, and diphenylmethane are effectively transformed into the corresponding aryl ketones, while amino and aldehyde functionalities remain intact, under air in the presence of cesium carbonate.
Key words
aerobic oxidation - oxygenation - arylalkanes - aryl ketones - cesium carbonate
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References
On leave from the Department of Chemistry, Chungnam National University, Daejeon 305-764, South Korea.