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Synthesis 2007(8): 1197-1203
DOI: 10.1055/s-2007-965977
DOI: 10.1055/s-2007-965977
PAPER
© Georg Thieme Verlag Stuttgart · New York
A One-Pot, Stereoselective Synthesis of 1,3- and 1,4-Dienyl Sulfones by Hydrostannylation-Stille Tandem Reaction of Tributyltin Hydride with Acetylenic Sulfones and Alkenyl or Allylic Halides
Further Information
Received
9 January 2007
Publication Date:
23 March 2007 (online)
Publication History
Publication Date:
23 March 2007 (online)
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Abstract
1,3-Dienyl and 1,4-dienyl sulfones can be stereoselectively synthesized in one pot under mild conditions, in good yields, by the palladium-catalyzed hydrostannylation of acetylenic sulfones, followed by Stille coupling with alkenyl or allylic halides, respectively.
Key words
acetylenic sulfone - hydrostannylation - Stille coupling - 1,3-dienyl sulfone - 1,4-dienyl sulfone
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