Bromodecarboxylation of (E)-3-Aryl-2-(diethoxyphosphoryl)acrylic Acids: A Facile Route to Diethyl Arylethynylphosphonates

Henryk Krawczyk; Łukasz Albrecht

doi:10.1055/s-2007-966057

PAPER

Bromodecarboxylation of (E)-3-Aryl-2-(diethoxyphosphoryl)acrylic Acids: A Facile Route to Diethyl Arylethynylphosphonates

Henryk Krawczyk*, Łukasz Albrecht
Institute of Organic Chemistry, Technical University (Politechnika), Żeromskiego 116, 90-924 ŁódŸ, Poland
Fax: +48(42)6365530; e-Mail: henkrawc@p.lodz.pl;

Abstract

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Abstract

Bromodecarboxylation of (E)-3-aryl-2-(diethoxyphosphoryl)acrylic acids leading to diethyl (Z)-2-aryl-1-bromovinylphosphonates has been conducted for the first time. The products have been shown to be useful for the synthesis of diethyl arylethynylphosphonates.

Key words

Hunsdiecker reaction - bromodecarboxylation - alk-1-ynylphosphonates - Oxone - acrylic acids

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