Synlett 2007(19): 3027-3031  
DOI: 10.1055/s-2007-990965
LETTER
© Georg Thieme Verlag Stuttgart · New York

Useful Preparation of 6-Phenyl-2,2′-Bipyridine Ligands Bearing Di-n-butylaminophenyl or Gallate Derivatives Substituted in the 3- or 4-Positions

Stéphane Diringa, Pascal Retailleaub, Raymond Ziessel*a
a LCM, ECPM/ULP, CNRS, 25 Rue Becquerel, 67087 Strasbourg Cedex 02, France
e-Mail: ziessel@chimie.u-strasbg.fr;
b Laboratoire de Cristallochimie, ICSN, CNRS, Bât 27, 1 Avenue de la Terrasse, 91198 Gif-sur-Yvette Cedex, France
Further Information

Publication History

Received 14 August 2007
Publication Date:
08 November 2007 (online)

Zoom Image

Abstract

A simple protocol for the efficient preparation of substituted 6-phenyl-2,2′-bipyridine derivatives is described. A reverse type of Diels-Alder reaction between a 6-phenyl-2-pyridyl-1,3,4-triazine and 4-N,N-di-n-butylaminophenyl- or gallate-ethynyl derivatives at high temperature provide a mixture of two products easily separable by column chromatography. A variety of ligands suitable for the synthesis of cyclometalated platinum complexes have been produced. Additional substitution of the Pt-Cl by various donor-acceptor ethynyl fragments is feasible by mean of copper(I) catalysis.

Crossref Cited-by logo
Article Citations