o-Benzenedisulfonimide as Reusable Brønsted Acid Catalyst for Acid-Catalyzed Organic Reactions

Margherita Barbero; Silvano Cadamuro; Stefano Dughera; Paolo Venturello

doi:10.1055/s-2008-1072564

PAPER

o-Benzenedisulfonimide as Reusable Brønsted Acid Catalyst for Acid-Catalyzed Organic Reactions

Margherita Barbero*, Silvano Cadamuro, Stefano Dughera, Paolo Venturello
Dipartimento di Chimica Generale e Chimica Organica, Università, Via P. Giuria 7, 10125 Torino, Italy
Fax: +39(11)6707642; e-Mail: margherita.barbero@unito.it;

Abstract

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Abstract

Acid-catalyzed organic reactions, such as etherification, esterification, acetal synthesis, cleavage, and interconversion, and pinacol rearrangement were carried out in the presence of catalytic amounts of o-benzenedisulfonimide as Brønsted acid catalyst; the conditions were mild and selective. The catalyst was easily recovered and purified, ready to be used in further reactions, with economic and ecological advantages.

Key words

acid catalysis - ether synthesis - ester synthesis - acetal synthesis - pinacol rearrangement

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References

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