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Synlett 2008(10): 1532-1536
DOI: 10.1055/s-2008-1078411
DOI: 10.1055/s-2008-1078411
LETTER
© Georg Thieme Verlag Stuttgart · New York
Synthesis of the Central Tryptophan-Leucine Residue of Celogentin C
Further Information
Publication History
Received
6 March 2008
Publication Date:
16 May 2008 (online)


Abstract
The synthesis of the central tryptophan residue of celogentin C is described featuring a Pd-catalyzed imine/enamine Heck-type reaction, a Pd-catalyzed Suzuki coupling, and an asymmetric Rh-catalyzed hydrogenation.
Key words
asymmetric catalysis - palladium - rhodium - natural products - total synthesis