DOI: 10.1055/s-00000084

Synthesis

Ausgabe Golden_Issue · Volume · 2019 DOI: 10.1055/s-008-42090

Virtual Golden Anniversary Issue

50 Years SYNTHESIS

Paul, Knochel: 50 Years SYNTHESIS – Golden Anniversary Issue
50 Years SYNTHESIS – Golden Anniversary Issue Part II
Trost, Barry M.; Schultz, Johnathan E.: Palladium-Catalyzed Asymmetric Allylic Alkylation Strategies for the Synthesis of Acyclic Tetrasubstituted Stereocenters
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Grogg, Marcel; Hilvert, Donald; Beck, Albert K.; Seebach, Dieter: Syntheses of Cyanophycin Segments for Investigations of Cell-Penetration
https://www.thieme-connect.de/media/synthesis/201901/i_z0415_ga_10-1055_s-0037-1610202.gif
Murai, Masahito; Takai, Kazuhiko: Unsymmetrical Difunctionalization of Two Different C–H Bonds in One Pot Under Transition-Metal Catalysis
https://www.thieme-connect.de/media/synthesis/201901/i_z0651_ga_10-1055_s-0037-1611066.gif
Karageorgis, George; Waldmann, Herbert: Guided by Evolution: Biology-Oriented Synthesis of Bioactive Compound Classes
https://www.thieme-connect.de/media/synthesis/201901/i_z0577_ga_10-1055_s-0037-1610368.gif
Barrett, Anthony G. M.; Ma, Tsz-Kan; Mies, Thomas: Recent Developments in Polyene Cyclizations and Their Applications in Natural Product Synthesis
https://www.thieme-connect.de/media/synthesis/201901/i_z0694_ga_10-1055_s-0037-1610382.gif
Zhang, Heng; Lei, Aiwen: Electrochemical/Photochemical Aminations Based on Oxidative Cross-Coupling between C–H and N–H
https://www.thieme-connect.de/media/synthesis/201901/i_z0696_ga_10-1055_s-0037-1610380.gif
Piccardi, Riccardo; Turcaud, Serge; Benedetti, Erica; Micouin, Laurent: Synthesis and Reactivity of Mixed Dimethylalkynylaluminum Reagents
https://www.thieme-connect.de/media/synthesis/201901/i_z0706_ga_10-1055_s-0037-1610392.gif
Kiefer, Alexander; Kazmaier, Uli: Syntheses of Cyclomarins – Interesting Marine Natural Products with Distinct Mode of Action towards Malaria and Tuberculosis
https://www.thieme-connect.de/media/synthesis/201901/i_z0668_ga_10-1055_s-0037-1610377.gif
Wu, Xiang; Gong, Liu-Zhu: Palladium(0)-Catalyzed Difunctionalization of 1,3-Dienes: From Racemic to Enantioselective
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Yoshikai, Naohiko: Recent Advances in Enantioselective C–C Bond Formation via Organocobalt Species
https://www.thieme-connect.de/media/synthesis/201901/i_z0719_ga_10-1055_s-0037-1610397.gif
Erb, William; Mongin, Florence: Twofold Ferrocene C–H Lithiations For One-Step Difunctionalizations
https://www.thieme-connect.de/media/synthesis/201901/i_z0724_ga_10-1055_s-0037-1610396.gif
Lübken, Dennis; Saxarra, Marius; Kalesse, Markus: Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications
https://www.thieme-connect.de/media/synthesis/201901/i_z0731_ga_10-1055_s-0037-1610393.jpg
Barde, E.; Guérinot, A.; Cossy, J.: α-Arylation of Amides from α-Halo Amides Using Metal-Catalyzed Cross-Coupling Reactions
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Kumagai, Naoya; Shibasaki, Masakatsu: 7-Azaindoline Auxiliary: A Versatile Attachment Facilitating Enantioselective­ C–C Bond-Forming Catalysis
https://www.thieme-connect.de/media/synthesis/201901/i_z0767_ga_10-1055_s-0037-1610412.gif
Stopka, Tobias; Adler, Pauline; Hagn, Gerhard; Zhang, Haoqi; Tona, Veronica; Maulide, Nuno: Electrophilic Activation of Amides for the Preparation of Poly­substituted Pyrimidines
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Supporting Information
Bartlett, Samuel L.; Keiter, Kimberly M.; Zavesky, Blane P.; Johnson, Jeffrey S.: Formation of Complex α-Imino Esters via Multihetero-Cope Rearrangement­ of α-Keto Ester Derived Nitrones
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Supporting Information
McCabe, Stephanie R.; Wipf, Peter: Asymmetric Total Synthesis and Biological Evaluation of (+)-Cycloclavine
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Supporting Information
Endoma-Arias, Mary Ann A.; Makarova, Mariia; Dela Paz, Helen E.; Hudlicky, Tomas: Chemoenzymatic Total Synthesis of (+)-Oxycodone from Phenethyl Acetate
https://www.thieme-connect.de/media/synthesis/201901/i_z0729_ga_10-1055_s-0037-1611335.gif
Supporting Information
Xue, Weichao; Oestreich, Martin: Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution
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Supporting Information
Sato, Io; Yamashita, Yasuhiro; Kobayashi, Shū: Alkylpotassium-Catalyzed Benzylic C–H Alkylation of Alkylarenes with Alkenes
https://www.thieme-connect.de/media/synthesis/201901/i_z0702_ga_10-1055_s-0037-1610378.gif
Supporting Information
Nitelet, Antoine; Kairouz, Vanessa; Lebel, Hélène; Charette, André B.; Evano, Gwilherm: Continuous Flow Chlorination of Alkenyl Iodides Promoted by Copper Tubing
https://www.thieme-connect.de/media/synthesis/201901/i_z0718_ga_10-1055_s-0037-1610398.gif
Supporting Information
Noguchi, Teppei; Nishii, Yuji; Miura, Masahiro: Rhodium-Catalyzed Cascade Annulative Coupling of 3,5-Diarylisoxazoles with Alkynes
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Supporting Information
Wang, Han; Zhang, Duo; Cao, Mengwei; Bolm, Carsten: Electrophilic Sulfoximidations of Thiols by Hypervalent Iodine Reagents
https://www.thieme-connect.de/media/synthesis/201901/i_z0566_ga_10-1055_s-0037-1610369.gif
Supporting Information
Gao, Wen-Chao; Xiong, Zi-Yue; Pirhaghani, Shafigh; Wirth, Thomas: Enantioselective Electrochemical Lactonization Using Chiral Iodoarenes as Mediators
https://www.thieme-connect.de/media/synthesis/201901/i_z0601_ga_10-1055_s-0037-1610373.gif
Supporting Information
Konstantinova, Olga V.; Koskinen, Ari M.P.: Synthesis of the C1–C12 Fragment of Calyculin C
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Supporting Information
Bartolo, Nicole D.; Hornstein, Alana L.; Zhao, Annie Y.; Woerpel, K. A.: Diastereoselectivities in Reductions of α-Alkoxy Ketones Are Not Always Correlated to Chelation-Induced Rate Acceleration
https://www.thieme-connect.de/media/synthesis/201901/i_z0695_ga_10-1055_s-0037-1610381.gif
Supporting Information
Krieck, Sven; Schüler, Philipp; Peschel, Jan M.; Westerhausen, Matthias: Straightforward One-Pot Syntheses of Silylamides of Magnesium and Calcium via an In Situ Grignard Metalation Method
https://www.thieme-connect.de/media/synthesis/201905/i_z0683_ga_10-1055_s-0037-1610407.jpg
Supporting Information
Stöckl, Yannick; Frey, Wolfgang; Lang, Johannes; Claasen, Birgit; Baro, Angelika; Laschat, Sabine: Asymmetric Organocatalysis Revisited: Taming Hydrindanes with Jørgensen–Hayashi Catalyst
https://www.thieme-connect.de/media/synthesis/201905/i_z0760_ga_10-1055_s-0037-1610409.gif
Supporting Information
Schober, Lukas; Ratnam, Shahilan; Yamashita, Yasunobu; Adebar, Niklas; Pieper, Matthias; Berkessel, Albrecht; Hessel, Volker; Gröger, Harald: An Asymmetric Organocatalytic Aldol Reaction of a Hydrophobic Aldehyde in Aqueous Medium Running in Flow Mode
https://www.thieme-connect.de/media/synthesis/201905/i_z0741_ga_10-1055_s-0037-1610404.gif
Gagosz, Fabien: Gold Vinylidenes as Useful Intermediates in Synthetic Organic Chemistry
https://www.thieme-connect.de/media/synthesis/201905/i_z0809_ga_10-1055_s-0037-1611647.gif
Zard, Samir Z.: Sulfur Betaines from S-Propargyl Xanthates. Unusual Chemistry from a Simple Functional Group
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Baldauf, Simon; Bode, Jeffrey W.: Synthesis and Evaluation of Cyclic Acetals of Serine Hydroxylamine for Amide-Forming KAHA Ligations
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Supporting Information
Leonov, Artem I.; Timofeeva, Daria S.; Ofial, Armin R.; Mayr, Herbert: Metal Enolates – Enamines – Enol Ethers: How Do Enolate Equivalents Differ in Nucleophilic Reactivity?
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Supporting Information
Crawford, Jennifer M.; Sigman, Matthew S.: Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element?
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Koeller, Julian; Gandeepan, Parthasarathy; Ackermann, Lutz: Visible-Light-Induced Decarboxylative C–H Adamantylation of Azoles at Ambient Temperature
https://www.thieme-connect.de/media/synthesis/201905/i_z0790_ga_10-1055_s-0037-1611633.gif
Supporting Information
Karlinskii, Bogdan Ya.; Romashov, Leonid V.; Galkin, Konstantin I.; Kislitsyn, Pavel G.; Ananikov, Valentine P.: Synthesis of 2-Azidomethyl-5-ethynylfuran: A New Bio-Derived Self-Clickable Building Block
https://www.thieme-connect.de/media/synthesis/201905/i_z0676_ga_10-1055_s-0037-1610414.gif
Supporting Information
Ueda, Mitsuhiro; Maeda, Ayami; Hamaoka, Kanako; Sasano, Mika; Fukuyama, Takahide; Ryu, Ilhyong: Bromine-Radical-Mediated Site-Selective Allylation of C(sp3)–H Bonds
https://www.thieme-connect.de/media/synthesis/201905/i_z0686_ga_10-1055_s-0037-1610413.gif
Supporting Information
Ferrer, Sofia; Echavarren, Antonio M.: Synthesis of Bullvalenes: Classical Approaches and Recent Developments
https://www.thieme-connect.de/media/synthesis/201905/i_z0791_ga_10-1055_s-0037-1611637.gif
McLellan, Ross; Uzelac, Marina; Bole, Leonie J.; Gil-Negrete, Jose María; Armstrong, David R.; Kennedy, Alan R.; Mulvey, Robert E.; Hevia, Eva: Alkali Metal Effects in Trans-Metal-Trapping (TMT): Comparing LiTMP with NaTMP in Cooperative MTMP/Ga(CH2SiMe3)3 Meta­lation Reactions
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Supporting Information
Hu, Fan; Ng, Jerome P. L.; Chiu, Pauline: Pyrroles as Dienes in (4+3) Cycloadditions
https://www.thieme-connect.de/media/synthesis/201905/i_z0864_ga_10-1055_s-0037-1611660.gif
Dohi, Toshifumi; Sasa, Hirotaka; Dochi, Mio; Yasui, Chihiro; Kita, Yasuyuki: Oxidative Coupling of N-Methoxyamides and Related Compounds toward Aromatic Hydrocarbons by Designer μ-Oxo Hypervalent Iodine Catalyst
https://www.thieme-connect.de/media/synthesis/201905/i_z0808_ga_10-1055_s-0037-1611661.gif
Lanza, Francesco; Pérez, Juana M.; Jumde, Ravindra P.; Harutyunyan, Syuzanna R.: Lewis Acid Promoted Trapping of Chiral Aza-enolates
https://www.thieme-connect.de/media/synthesis/201905/i_z0823_ga_10-1055_s-0037-1611657.gif
Supporting Information
Wiegand, Anja; Wiese, Vera; Glowacki, Britta; Iovkova, Ljuba; Schirrmacher, Ralf; Jurkschat, Klaus; Krause, Norbert: GlucoSiFA and LactoSiFA: New Types of Carbohydrate-Tagged Silicon-Based Fluoride Acceptors for 18F-Positron Emission Tomography (PET)
https://www.thieme-connect.de/media/synthesis/201905/i_z0819_ga_10-1055_s-0037-1611656.gif
Supporting Information
Kurandina, Daria; Chuentragool, Padon; Gevorgyan, Vladimir: Transition-Metal-Catalyzed Alkyl Heck-Type Reactions
https://www.thieme-connect.de/media/synthesis/201905/i_z0870_ga_10-1055_s-0037-1611659.gif
Sun, Alexandra C.; McAtee, Rory C.; McClain, Edward J.; Stephenson, Corey R. J.: Advancements in Visible-Light-Enabled Radical C(sp)2–H Alkylation of (Hetero)arenes
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Cecchini, Chiara; Lanzi, Matteo; Cera, Gianpiero; Malacria, Max; Maestri, Giovanni: Complementary Reactivity of 1,6-Enynes with All-Metal Aromatic Trinuclear Complexes and Carboxylic Acids
https://www.thieme-connect.de/media/synthesis/201905/i_z0806_ga_10-1055_s-0037-1611653.gif
Supporting Information
Spránitz, Péter; Sőregi, Petra; Botlik, Bence Béla; Berta, Máté; Soós, Tibor: Organocatalytic Desymmetrisation of Fittig’s Lactones: Deuterium as a Reporter Tag for Hidden Racemisation
https://www.thieme-connect.de/media/synthesis/201905/i_z0845_ga_10-1055_s-0037-1611655.gif
Matsuoka, Seiya; Nakamura, Kayo; Ohmori, Ken; Suzuki, Keisuke: General Synthetic Approach to Rotenoids via Stereospecific, Group-Selective 1,2-Rearrangement and Dual SNAr Cyclizations of Aryl Fluorides
https://www.thieme-connect.de/media/synthesis/201905/i_z0846_ga_10-1055_s-0037-1611654.gif
Supporting Information
Groso, Emilia J.; Schindler, Corinna S.: Recent Advances in the Application of Ring-Closing Metathesis for the Synthesis of Unsaturated Nitrogen Heterocycles
https://www.thieme-connect.de/media/synthesis/201905/i_z0835_ga_10-1055_s-0037-1611651.gif
Radtke, M. Alex; Dudley, Caroline C.; O’Leary, Jacob M.; Lambert, Tristan H.: A Scalable, One-Pot Synthesis of 1,2,3,4,5-Pentacarbomethoxycyclopentadiene
https://www.thieme-connect.de/media/synthesis/201905/i_z0826_ga_10-1055_s-0037-1611650.gif
Maraswami, Manikantha; Loh, Teck-Peng: Transition-Metal-Catalyzed Alkenyl sp2 C–H Activation: A Short Account
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Blank, Lena; Fagnoni, Maurizio; Protti, Stefano; Rueping, Magnus: Visible Light-Promoted Formation of C–B and C–S Bonds under Metal- and Photocatalyst-Free Conditions
https://www.thieme-connect.de/media/synthesis/201905/i_z0804_ga_10-1055_s-0037-1611648.gif
Supporting Information
Blieck, Rémi; Perego, Luca Alessandro; Ciofini, Ilaria; Grimaud, Laurence; Taillefer, Marc; Monnier, Florian: Copper-Catalysed Hydroamination of N-Allenylsulfonamides: The Key Role of Ancillary Coordinating Groups
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Supporting Information