Synlett 2016; 27(03): 471-476
DOI: 10.1055/s-0035-1560812
letter
© Georg Thieme Verlag Stuttgart · New York

Iron-Catalyzed Cross-Coupling of Benzylic Manganese Chlorides with Aryl and Heteroaryl Halides

Andreas D. Benischke
a   Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstr. 5–13, 81377 Munich, Germany   Email: Paul.Knochel@cup.uni-muenchen.de
,
Antoine J. A. Breuillac
b   Institut de Recherche de Chimie Paris, CNRS, Chimie ParisTech, 11 Rue Pierre et Marie Curie, 75005 Paris, France
,
Alban Moyeux
b   Institut de Recherche de Chimie Paris, CNRS, Chimie ParisTech, 11 Rue Pierre et Marie Curie, 75005 Paris, France
c   Université Paris 13, Sorbonne Paris Cité, 74 Rue Marcel Cachin, 93017 Bobigny, France
,
Gérard Cahiez
b   Institut de Recherche de Chimie Paris, CNRS, Chimie ParisTech, 11 Rue Pierre et Marie Curie, 75005 Paris, France
,
Paul Knochel*
a   Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstr. 5–13, 81377 Munich, Germany   Email: Paul.Knochel@cup.uni-muenchen.de
› Author Affiliations
Further Information

Publication History

Received: 30 July 2015

Accepted after revision: 02 October 2015

Publication Date:
22 October 2015 (online)


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Abstract

The use of FeCl2 (10 mol%) allows a convenient iron-catalyzed cross-coupling reaction of benzylic manganese(II) chlorides with various aryl and heteroaryl chlorides, bromides and iodides leading to polyfunctionalized diaryl- and arylheteroarylmethane derivatives.

Supporting Information