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CC BY-NC-ND 4.0 · Synlett 2023; 34(12): 1356-1366
DOI: 10.1055/a-1987-6464
DOI: 10.1055/a-1987-6464
account
Special Issue Honoring Masahiro Murakami’s Contributions to Science
Versatile Utility of Cp*Co(III) Catalysts in C–H Amination under Inner- and Outer-Sphere Pathway
This research was supported by the Institute for Basic Science (IBS-R010-D1).
Dedicated to Professor Masahiro Murakami
Abstract
This Account describes the recent advances in our research program toward the development of cobalt-catalyzed C–H amidation reactions. In particular, synthetic versatilities of obtainable amino products shown to be achieved on the basis of two distinctive mechanistic scaffolds; inner- and outer-sphere pathways. It highlights our approaches to transit the modes of C–N bond formation by introduction of bidentate LX-type ligands into Cp*Co(III) precursors, thereby broadly expanding the scope of amination reactions.
1 Introduction
2 Cp*Co-Catalyzed Inner-Sphere C–H Amidation
3 Cp*Co-Catalyzed Outer-Sphere C–H Amidation
3.1 C(sp2)–N Bond Formation
3.2 C(sp3)–N Bond Formation
4 Conclusion
Key words
cobalt catalysis - C–H amidation - chelation-assisted amidation - nitrenoid insertion - site-selective amidationPublication History
Received: 31 October 2022
Accepted after revision: 24 November 2022
Accepted Manuscript online:
25 November 2022
Article published online:
11 January 2023
© 2022. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution-NonDerivative-NonCommercial-License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by-nc-nd/4.0/)
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