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Synlett 2009(14): 2205-2216
DOI: 10.1055/s-0029-1217554
DOI: 10.1055/s-0029-1217554
ACCOUNT
© Georg Thieme Verlag
Stuttgart ˙ New York
Synthesis of Fluorinated Arenes and Hetarenes Based on One-Pot Cyclizations of 1,3-Bis(trimethylsilyloxy)-1,3-butadienes
Further Information
Received
3 February 2009
Publication Date:
10 July 2009 (online)
Publication History
Publication Date:
10 July 2009 (online)
Abstract
One-pot cyclizations of fluorinated 1,3-bis(silyloxy)-1,3-butadienes and 3-alkoxy- and 3-silyloxy-2-en-1-ones provide a convenient access to various fluoro-, trifluoromethyl- and perfluoroalkyl-substituted arenes and hetarenes.
1 Introduction
2 [3+3]-Type Cyclizations of Fluorinated Enones
3 [3+3]-Type Cyclizations of Trifluoromethyl-Substituted Enones
4 [3+3]-Type Cyclizations of Perfluoroalkyl-Substituted Enones
5 [3+2]-Type Cyclizations of Fluorinated 1,3-Bis(silyloxy)-1,3-butadienes
6 [4+2]-Type Cyclizations of Fluorinated 1,3-Bis(silyloxy)-1,3-butadienes
7 Summary
Key words
arenes - heterocycles - cyclizations - organofluorine compounds - silyl enol ethers
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References
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