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Synthesis 2014; 46(17): 2258-2271
DOI: 10.1055/s-0034-1378373
DOI: 10.1055/s-0034-1378373
short review
Recent Advances in Electrophilic Amination Reactions
Further Information
Publication History
Received: 26 March 2014
Accepted after revision: 09 June 2014
Publication Date:
15 July 2014 (online)
Abstract
Electrophilic nitrogen sources are an increasingly popular class of reagents for the formation of C–N bonds. Recently, a significant number of useful methodologies have been reported, in particular, examples using transition-metal catalysis. This review summarizes the latest developments in this field, with a focus on very recent advances.
1 Introduction
2 Reactions with Stoichiometric Organometallic Reagents
2.1 Organoboron Nucleophiles
2.2 Zirconium Derivatives
2.3 Silicon Derivatives
2.4 Grignard Reagents
2.5 Organozinc Reagents
3 Catalytic Organometallic Species
3.1 C–H Activation Reactions
3.2 Heterocycle Synthesis via Addition/Amination Sequences
3.3 Narasaka–Heck (or Amino-Heck) Reactions
4 Enolates as Nucleophiles
5 Conclusion
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