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Synlett 2016; 27(05): 714-723
DOI: 10.1055/s-0035-1561297
DOI: 10.1055/s-0035-1561297
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Experimental and Calculated Electrochemical Potentials of Common Organic Molecules for Applications to Single-Electron Redox Chemistry
Further Information
Publication History
Received: 23 October 2015
Accepted after revision: 24 November 2015
Publication Date:
23 December 2015 (online)
Abstract
Herein, we report half-peak potentials for over 180 organic substrates obtained via cyclic voltammetry. These values are of great use in assessing the thermodynamics of an electron-transfer process. In addition, we disclose a simple computational method to determine redox potentials of organic substrates.
Key words
cyclic voltammetry - photoredox catalysis - redox potential - electron transfer - computational chemistrySupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1561297.
- Supporting Information
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