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Synlett 2016; 27(09): 1433-1437
DOI: 10.1055/s-0035-1561356
DOI: 10.1055/s-0035-1561356
letter
Amine-functionalized Metal-Organic Frameworks: An Efficient and Recyclable Heterogeneous Catalyst for the Knoevenagel Condensation Reaction
Further Information
Publication History
Received: 03 December 2016
Accepted after revision: 12 January 2016
Publication Date:
05 February 2016 (online)
Abstract
A highly efficient and reusable catalyst based on metal-organic frameworks (MOF) has been synthesized by post-functionalization and applied in Knoevenagel condensations of various aldehydes and ketones. The catalytic efficiency was demonstrated by the high conversion (over 85−98%) of the reactants under mild conditions. The catalyst maintained its unique framework after the reaction and could be recycled and reused several times without significant loss of activity.
Key words
Knoevenagel condensation - metal-organic frameworks - heterogeneous catalysis - carbon–carbon bond - aldehyde - ketoneSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1561356.
- Supporting Information
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