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Synthesis 2021; 53(06): 983-1002
DOI: 10.1055/s-0040-1705986
DOI: 10.1055/s-0040-1705986
review
Transition-Metal-Catalyzed Cross-Coupling Reactions of Grignard Reagents
The research reported in this paper and carried out at BME has been supported by the NRDI Fund (TKP2020 NC, Grant No. BME-NC) based on the charter of bolster issued by the NRDI Office under the auspices of the Ministry for Innovation and Technology.
Abstract
Transition-metal-catalyzed cross-coupling of organohalides, ethers, sulfides, amines, and alcohols (and derivatives thereof) with Grignard reagents, known as the Kumada–Tamao–Corriu reaction, can be used to prepare important intermediates in the synthesis of numerous biologically active compounds. The most frequently used transition metals are nickel, palladium, and iron, but there are several examples for cross-coupling reactions catalyzed by copper, cobalt, manganese, chromium, etc. salts and complexes. The aim of this review is to summarize the most important transition-metal-catalyzed cross-coupling reactions realized in the period 2000 to 2020.
1 Introduction
2 Nickel Catalysis
3 Palladium Catalysis
4 Iron Catalysis
5 Catalysis by Other Transition Metals
5.1 Cobalt Catalysis
5.2 Copper Catalysis
5.3 Manganese Catalysis
5.4 Chromium Catalysis
6 Conclusion
Key words
transition metals - Grignard reagent - cross-coupling - organometallic reagent - organic halides - Kumada–Tamao–Corriu couplingPublication History
Received: 01 September 2020
Accepted after revision: 19 October 2020
Article published online:
10 December 2020
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