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Synlett 2023; 34(10): 1079-1086
DOI: 10.1055/s-0042-1751426
DOI: 10.1055/s-0042-1751426
synpacts
Synthesis and Coordination Chemistry of Fluorinated Cyclopentadienyl Ligands
Funded by the Deutsche Forschungsgemeinschaft (DFG, Project number 387284271 – SFB 1349).
Abstract
The incorporation of fluorinated substituents in cyclopentadienyl anions leads to distinct changes in the properties of the corresponding metal complexes, e.g., with regards to electrochemical properties or metal–ligand bonding energies. This review summarizes the synthetic challenges of the preparation and coordination of fluorinated cyclopentadienyl anions.
1 Introduction
2 Fluorinated Cyclopentadienyls
3 Cyclopentadienyls with One CF3 Group
4 Cyclopentadienyls with Four CF3 Groups
5 Cyclopentadienyls with Five CF3 Groups
6 Cyclopentadienyls with ‘Fluorous Ponytails’
7 Cyclopentadienyls with C6F5 Groups
8 Trends in Interaction Energies
9 Conclusion
Key words
cyclopentadienes - fluorine - ligands - metallocenes - substituent effect - transition metalsPublication History
Received: 20 January 2023
Accepted after revision: 06 February 2023
Article published online:
28 February 2023
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