Synlett

Issue eFirst

Lang, Yatao; Li, Chao-Jun; Zeng, Huiying: Dearomatization–Rearomatization Strategy for Palladium-Catalyzed C–N Cross-Coupling Reactions

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Li, Xiangdong; Waser, Jérôme: Unlocking σ-Type Cyclopropenium Cation Transfer Reactions by an Iodine(III)-Based Umpolung Strategy

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Müller, Nicolas; Kováč, Ondřej; Rode, Alexander; Atzl, Daniel; Magauer, Thomas: Development of a Triethylborane-Mediated Giese Cyclization/Aldol Reaction Cascade for the Total Synthesis of Ganoapplanin

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Chen, Jiajia; Shi, Hang: Catalytic Nucleophilic Aromatic Substitution Amination of 2-Aminopyridines with Amines

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Fukui, Norihito: Constructing Figure-Eight Structures by Inner-Bond Cleavage

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Pal, Amit; Biswas, Sourav; Sahoo, Basudev; Negishi, Yuichi: Cu-Nanoclusters as Emerging Catalyst in Organic Synthesis

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Singh, Brandon; Ting, Chi P.: Enzymatic Peroxidation in the Chemoenzymatic Synthesis of 13-Oxoverruculogen

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Yuan, Fushan; Yan, Xufei; Xia, Ying: Enantioselective Synthesis of Cyclobutylboronates

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Morrow, Andrew P.; Smith, Myles W.: Total Synthesis of the Psammaplysins: Evolution of a Dipolar Cycloaddition Approach

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Tran, Minh-Khoa; Ready, Joseph M.: Advances in the 1,2-Metalate Rearrangement Chemistry of Alkenylboronates

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Willcox, Dominic R.: Synthesis of Silyl Heterocycles Using Transborylation

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Jiang, Yuan-Xu; Liao, Li-Li; Ye, Jian-Heng; Yu, Da-Gang: Visible-Light-Driven Thiolate-Catalyzed Carboxylation of C(sp²)–H Bonds in Azines with Carbon Dioxide

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Ge, Liang; Liu, Yangbin; Feng, Xiaoming: Iron-Catalyzed Three-Component Asymmetric Carboazidation of Alkenes with Alkanes and Trimethylsilyl Azide

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Hou, Liuzhen; Yang, Longqing; Liu, Xiaohua; Cao, Weidi; Feng, Xiaoming: Visible-Light-Induced Enantioselective Dearomative [2+2]-Cycloaddition/Ring-Expansion Sequence of Indoles with Simple Alkenes

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Jana, Kalipada; Sparr, Christof: Enantioselective Wittig Reactions Controlled by P^III/P^V=O Redox Catalysis Open Access

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Cai, Chen-Yan; Qin, Tian: An Oxygen Walk Approach for C3 Selective Hydroxylation of Pyridines

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Yang, Shuang; Fang, Xinqiang: BMIDA-Directed Catalytic Asymmetric Transfer Hydrogenation for Enantioselective Access to α-Boryl Alcohols

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Shimose, Asuha; Nagashima, Yuki: Photoinduced Dearomative Multiple Functionalization of Quinolines to Construct Highly Substituted 3D Frameworks

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Yang, Xingheng; Zhang, Chi; Wang, Cheng-Qiang; Feng, Chao: Expedient Access to Structural Complexity via Radical β-Fragmentation of N–O Bonds

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Li, Juan; Song, Jin; Guo, Chang: Enantioselective Electrocatalytic Nitroalkylation

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Denkler, Luca Mareen; Shekar, Meghana Aladahalli; Bunescu, Ala: Iron-Photocatalyzed Decarboxylative Oxygenation of Aliphatic Carboxylic Acids

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Zhao, Zhi; Zhu, Lei; Song, Zhao-Li; Qubi, Keji; Ouyang, Qin; Du, Wei; Chen, Ying-Chun: Asymmetric [3+2] Annulations of Propargylic Carbonates and Vinylogous Nucleophiles via a Nickel-Catalyzed Alkenylation Pathway

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Issue Accepted Manuscripts

Gupta, Harshit; Saunkhla, Rajat; Indra, Arindam: The scope and prospect of photoelectrochemistry for C‒H bond activation using semiconductor photoanodes

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Jacob, Clément; Annibaletto, Julien; Theunissen, Cédric: Photoredox-Catalyzed Reductive Activation of Ammonium Salts

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Bhatt, Kamal; Seidel, Daniel: Cyclic Imine-BF3 Complexes as Precursors for Functionalized Azacycles

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Aida, Kazuhiro; Ota, Eisuke; Yamaguchi, Junichiro: Reductive Ring Opening of Cyclic Amines: Pyrrolidines and Beyond

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Wang, Xiao-XIa; Jiao, Lei: Palladium-Catalyzed Ortho-Alkylation of Iodoarenes Enabled by a Cooperative Cycloolefin Ligand and a Bulky Trialkylphosphine

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Lu, Xi; Huang, Yuyang; Yang, Yuxing; Shu, Chao: Advances in the Synthesis of S-containing Cyclic Architectures via Insertion of SO2

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Wang, Sheng; Guo, Peng; Shu, Xing-Zhong: Unlocking C–OH Bond Activation for Radical C-Glycosylation of Native Saccharides

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Zhang, Zhuzhu; Qin, Jian; Zhu, Shengqing; Chu, Lingling: Divergent Carbocyanation and Hydrocyanation of Alkynes Enabled by Photoinduced Nickel-Catalyzed Homolytic Bond Cleavage of C(sp3)-N Bond in Isonitriles

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Zhang, Jie; Shi, Zhuangzhi: Nickel-Catalyzed Deuteroalkylation Using Thianthrenium Salts

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Fang, Shuai-Shuai; shang, ming: A Ligand-Controlled Strategy for the Stereoselective Synthesis of P-Stereogenic ProTides

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Issue 07/2025

Ding, Yongzheng; Huang, Hanmin: The Development of Radical/Palladium Relay Catalysis for C–H Carbonylation

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Semenya, Julius; Yang, Yuanjie; Picazo, Elias: Iron-Catalyzed Cross-Electrophile Coupling

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G.-Simonian, Nicolas; Spieß, Philipp; Kaiser, Daniel; Maulide, Nuno: Stereocontrolled Synthesis of 1,4-Dicarbonyls via [3,3]-Sulfonium Rearrangement and Application to the Synthesis of Heterocycles

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Wang, Ming-Yang; Li, Wei: Dearomative Carbonylations of Arenes via Bifunctional Coordination to Cr(CO)₃

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Zhao, Jie: Investigating the Photoactivity of Low-Valent Zirconium Catalyst in Ether Activation

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Linker, Torsten: Recent Synthetic Applications of the Birch Reduction

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Cheng, Buqing; Xu, Zhen; Huo, Haohua: Nickel-Catalyzed, Bromine-Radical-Promoted Enantioselective C(sp³)–H Cross-Couplings

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Yang, Hui; Chen, Jie; Zhou, Ling: Lewis Acid Catalyzed Cycloaddition Reaction of Bicyclo[1.1.0]butanes

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Paroi, Bidisha; Patil, Nitin T.: Gold-Catalyzed Cope Rearrangements

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Issue 06/2025

Kaswan, Poonam: Tellurenated Compounds: Synthesis and Application in Ion Detection and as a Catalyst

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Smith, Joel M.: Heterocyclic Surgery for Isotopic Labeling

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Isbrandt, Eric S.; Newman, Stephen G.: 1,5-Diaza-3,7-diphosphacyclooctanes (P₂N₂): An Underappreciated Ligand Class for Nickel- and Palladium-Catalyzed Heck-Type Cross-Couplings

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Li, Yan; Lu, Xi: Cobalt-Catalyzed Regio- and Enantioselective Hydroalkylation of 1,1-Disubstituted Styrenes

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Feng, Jian-Jun: Recent Progress in (3+3) Cycloadditions of Bicyclobutanes to Access Bicyclo[3.1.1]heptane Derivatives

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Brunard, Erwan; Boquet, Vincent; Bissonnier, Théo; Saget, Tanguy; Carrizo, E. Daiann Sosa; Sircoglou, Marie; Dauban, Philippe: Catalyst-Controlled Strategies to Override the Bond Dissociation Energy-Driven Selectivity of Benzylic C(sp³)–H Insertions

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Yang, Peng-Fei; Zhao, Han-Tong; Shu, Wei: Asymmetric Alkyl-Alkyl Cross-Coupling Enabled by Ni-Catalyzed Cross-Hydrodimerization of Enamides with Unactivated Alkenes

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Issue 05/2025

Guo, Haoxin; Rajca, Andrzej: Chiral π-Conjugated Double Helical Aminyl Diradical with the Triplet Ground State

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Li, Pengfei; Qiu, Youai: Reductive Electrophilic Cross-Coupling for Constructing C(sp³)–C(sp³) Bonds

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Zeng, Jun; Li, Yajie; Li, Feiyan; Zhou, Sisi: Comparison of the Activity for Theaflavin Production by a Recombinant Polyphenol Oxidase and a Commercial Enzyme

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Issue 04/2025

Joven-Sancho, Daniel; Nebra, Noel: On the Existence and Relevance of Copper(III) Fluorides in Oxidative Trifluoromethylation

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Yang, Hongzhi; Nguyen, Truc Quynh; Tang, Yefeng: Chiral-Bisphosphine-Catalyzed Asymmetric Staudinger/Aza-Wittig Reaction: Development, Mechanism Study, and Synthetic Application

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Issue 03/2025

Zhang, Jiyao; Huang, Haohao; Zuo, Zhijun: Photoredox- and Cobalt-Cocatalyzed Dehydrogenative Ring-Opening/Functionalization of Monodonor Cyclopropanes

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Cong, Fei; Ng, Jun Wei; Koh, Ming Joo: A Homolytic Substitution Approach for Directing Group-Free Nickel-Catalyzed Dialkylation of Unactivated Alkenes

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Issue 02/2025

Kim, Minseok; Han, Seunghoon; Hong, Sungwoo: Nickel-Catalyzed Regio- and Enantioselective Hydrofluorination in Unactivated Alkenes

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Huang, Ming-Yao; Zhu, Shou-Fei: Enantioselective α-Boryl Carbene Transformations

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Issue 01/2025

Ma, Jin-Tao; Xiao, Li-Jun: Nickel-Catalyzed Asymmetric Borylative Coupling of 1,3-Dienes with Aldehydes

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Sakthivel, Pandaram; Shi, Qinglong; Ye, Juntao: Chiral Sulfones via Single-Electron Oxidation-Initiated Photoenzymatic Catalysis

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Issue 19/2024

Lou, Xiangyu; Lin, Jiaxin; Lyu, Hairong: Stereoselective Synthesis of Unsymmetrical 1,1-Diborylalkenes

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Issue 18/2024

Bagnall, Nicholas R.; Jones, Meredith H.; Donovan, Brian R.; Worrell, Brady T.: Catalytic Chain Transfer in Crosslinking Photopolymerizations

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Gonzalez, Fernando; De Leon, Edgardo; Shoshani, Manar M.: Accessing Reactive Metal Hydrides through Designed Heterometallic Bridges

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Issue 17/2024

Yuan, Pan-Feng; Meng, Qing-Yuan: Carboxylation of Alkenes with CO₂ via Photocatalytic Cleavage of C=C Double Bonds

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Liu, Zhaoxin; Ren, Yi: Design of Indole-Functionalized Phosphepines towards New Organic Chromophores

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Issue 16/2024

Käch, Daniel; Bezdek, Máté J.: A Redox Tale of Two Phosphine Oxides (and a Terthiophene)

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Chen, Ang; Ji, Chong-Lei; Gao, De-Wei: Precision Alkynylation of 1,3-Bis(Boronates) by Utilizing Distinct Organometallic Reagents for Regioselective Synthesis

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Issue 15/2024

Haines, Christopher A.; Han, Jian; Nacsa, Eric D.: Esterification as a Demonstration of Electrochemically Powered Catalytic Dehydration

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Malinčík, Juraj; Šolomek, Tomáš: Topological Bistability of the π-System in a Helicene Carbon Nanohoop Open Access

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Issue 14/2024

Zhang, Cijun; Fu, Xuancheng; Hu, Xiaoran: Harnessing the Conformer/Atropisomer-Dependent Photochromism of Diarylethene Photoswitches and Forcing a Diarylethene Atropisomer to Its Configurational Diastereomers with Polymer Mechanochemistry

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Song, Shuaishuai; Zhou, Wang: Methods for the Synthesis of 1-Indanones Containing a β-Quaternary Carbon Center

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Rodríguez, Paula; Duran, Jordi; Gisbert, Martí; Companyó, Xavier: Defluorinative Asymmetric Allylic Alkylations

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Issue 13/2024

Chen, Jingyi; Lei, Tao; Wan, Danyang; Yang, Yudong: Construction of Bibenzothiophenes through Oxidative C–H Cyclization with 1,3-Diynes

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Levin, Mark D.: Retrosynthetic Simplicity FREE ACCESS

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Baire, Beeraiah; Mishra, Surabhi; Roy, Debayan: Chiral Cyclodimerization Reactions: Construction of Nonnatural Dimeric Carbazoles from (±)-4-Methylene-3-hydroxytetrahydrocarbazoles

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Issue 12/2024

Huang, Zhongxing: Construction of Vicinal Stereocenters via Asymmetric Cyanosilylation

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Serafino, Andrea; Maestri, Giovanni: A Complementary Route for Alkene–Arene para-Cycloadditions by Visible-Light-Promoted Triplet Sensitization of Allenamides

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Ma, Zhan-Cai; Huang, Yuan: Pd-catalyzed Stereodivergent [4+2] Annulation to Access [6.7]-Fused N-Heterocycles

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Issue 10/2024

Nitsche, Christoph: The Cyanopyridine–Aminothiol Click Reaction: Expanding Horizons in Chemical Biology

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Issue 07/2024

Dalkılıç, Erdin; Güneş, Yakup: Solvent Effect on Base-Free Synthesis 4-Substituted 2-Oxazolines via Intramolecular Cyclodemesylation

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Kang, Jie; Ren, Simu; Su, Bo: Synthesis of P-Chiral Tertiary Phosphine Oxides by Copper-Catalyzed Dynamic Kinetic Asymmetric C–P Cross-Coupling

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Plasek, Erin E.; Denman, Brylon N.; Roberts, Courtney C.: Insights into the Regioselectivity of Metal-Catalyzed Aryne Reactions

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Issue 02/2024

Kang, Dahye; Kim, Justin: Enamine N-Oxides: Design, Synthesis, and Function in Bioortho­gonal Reactions

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Xie, Xiaolan; Hou, Na; Lin, Yan; Lei, Jian: Synthesis of Ynamides by C(sp)–H Amidation

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Tsuzuki, Saori; Kano, Taichi: Practical Asymmetric Synthesis of Sulfoximines and Sulfimides from Sulfinamides

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Issue 19/2023

Huang, Wenbin; He, Zikai: Initialing Circularly Polarized Room-Temperature Phosphorescence from Purely Organic Luminophore Aggregate

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Yang, Ming: The Total Synthesis of Mollanol A by a Convergent Strategy

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Issue 17/2023

Saito, Fumito: A Sulfoxide Reagent for Sulfinylative Cross-Coupling

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Zhu, Zhiming; Deng, Zhengxi; Ouyang, Xinke; Shu, Chao: New Advances in Sultine Chemistry

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Wei, Yi-Ming; Ma, Xiao-Di; Duan, Xin-Fang: ortho-Heterobimetallic Arylene Complex: A New Platform for Regioselective Difunctionalization

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Issue 16/2023

Taniguchi, Tohru: Vibrational Circular Dichroism Studies on Axially Chiral Carbodiimides and Allenes

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Shi, Bin; Xiao, Wen-Jing; Lu, Liang-Qiu: Palladium-Catalyzed Asymmetric Cycloaddition/Cope Rearrangement Relay: Synthesis of Chiral Endocyclic Allenes

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Issue 15/2023

Baek, Heeyoel; Yamada, Yoichi M. A.: Development of Silicon Nanowire Array–Metal Hybrid Catalysts for Batch and Flow Organic Reactions

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You, Mengwei; Bian, Tiancen; Zhou, Liejin; Zhang, Zuxiao: Accessing Aryldifluoromethyl Derivatives through Alkene Insertion into Benzylic C–F Bonds

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Issue 14/2023

Wise, Dan E.; Parasram, Marvin: Photoexcited Nitroarenes as Anaerobic Oxygen Atom Transfer ­Reagents

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Margarita, Cristiana; Di Francesco, Davide; Lundberg, Helena: Catalytic Dehydrative Transformations Mediated by Moisture-Tolerant Zirconocene Triflate Open Access

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Issue 13/2023

Xu, Fan; Smith, Myles W.: 2,2-Disubstituted Indoxyls via Oxidative Dearomatization: Generalization to 2-Alkylindoles and Application to Alkaloid Synthesis

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Li, Liubo; Fu, Niankai: Taming Challenging Radical-Based Convergent Paired Electrolysis with Dual-Transition-Metal Catalysis

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Issue 11/2023

Zhang, Yang; Sigrist, Michel; Martínez, Sebastián; Bojanowski, Jan; Antheaume, Cyril; Granda, Jarosław M.; Dydio, Paweł: Iodide-Assisted Pd Catalysis as an Attractive Alternative to Rh Catalysis for the Industrially Relevant Isoselective Hydroformylation of Simple Aliphatic Alkenes

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Huang, Guanghao; Kouklovsky, Cyrille; de la Torre, Aurélien: Retro-[4+2]/Intramolecular Diels–Alder Cascade Allows a Concise Total Synthesis of Lucidumone

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Issue 10/2023

Xu, Wenhao; Zhou, Liejin; XU, Tao: Deoxygenative Alkylboration of Aldehydes to Synthesize Versatile Secondary α,α-Dialkyl Boronates

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Sievers, Robin; Parche, Joshua; Kub, Nico G.; Malischewski, Moritz: Synthesis and Coordination Chemistry of Fluorinated Cyclopentadienyl Ligands

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Issue 09/2023

Nieland, Esther; Voss, Jona; Schmidt, Bernd M.: Shining a Light on Dissipative Supramolecular Assemblies

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Park, Jinhwan; Jang, Dongkyu; An, Jihye; Park, Yeongmi; Bae, Hyeonwoong; Kim, Minseok; Lee, Joohyun; Son, Jongwoo: Copper(I)-Mediated Decarboxylative N-Arylation of Dioxazolones: Synthesis of N-Aryl Amides

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Issue 08/2023

Cai, Yue-Ming; Shang, Ming: Enantioselective Alkylation of Amino Acid Derivatives with ­Unactivated Olefins via C–N Bond Cleavage

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Liang, Hao; Wang, Jun: Chiral Bicyclo[2.2.2]octane-Fused and Ferrocene-Derived Cyclopentadienyl Ligands for Asymmetric C–H Activation

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Issue 07/2023

Pradhan, Chandini; Punji, Benudhar: Advances in the Iron-Catalyzed Direct Functionalizations of ­Heterocycles

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Issue 05/2023

Li, Zhi-Qiang; Zhang, Chi; Feng, Chao: Photoredox-Catalysis-Enabled Ring-Opening Functionalization of Aryl Cyclopropanes

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Ascaso-Alegre, Christian; Mangas-Sánchez, Juan: Cascade Processes Merging Chemical and Enzyme Catalysis

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Issue 04/2023

Xu, Ying; Li, Ling; Zhao, Min; Jiang, Yaojia: Reassembly of Unsaturated C–C Bonds by a Cutting/Insertion Cascade

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Tan, Fen; He, Xiao-Yu; Yang, Qing-Qing; Zou, You-Quan: Asymmetric Formal [3+2] Cycloaddition Reactions of 3-Isothio­cyanato Oxindoles: an Update

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Issue 03/2023

Ćorković, Andrej; Dorian, Andreas; Williams, Florence J.: Improvements in Efficiency and Selectivity for C–F Bond Halogen-Exchange Reactions by Using Boron Reagents

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Ferjancic, Zorana B.; Bihelovic, Filip J.: Total Synthesis of (+)-Alstonlarsine A: Old Reactions in Modern Alkaloids Synthesis

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Issue 02/2023

Jia, Si-Ming; Huang, Yi-Hang; Wang, Fei: Aminium-Radical-Mediated Intermolecular Hydroamination of Nonactivated Olefins

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Antoniak, Damian; Barbasiewicz, Michał: Reactions of Nitroarenes with Corey–Chaykovsky Reagents

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Issue 01/2023

Zhu, Yulei; Zeng, Yaxin; Jiang, Zhong-Tao; Xia, Ying: Recent Advances in Transition-Metal-Catalyzed Cross-Coupling Reactions of gem-Difluorinated Cyclopropanes

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Sun, Ling-Zhi; Xie, Jian-Bo: Rhodium-Catalyzed Ring Expansion and Ring Opening of ­Azetidines: Domino Conjugate Addition/Inert-Bond Activation

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Issue 20/2022

Lam, Kevin: Electrosynthesis: A Practical Way to Access Highly Reactive Intermediates

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Sun, Qianlin; Luo, Yuncong; Xu, Xin: Transition-Metal-Catalyzed Regioselective C–H Borylation of ­Pyridines

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Issue 19/2022

Tao, Ling-Fei; Qian, Linghui; Liao, Jia-Yu: Catalytic Asymmetric [3+3] Cycloaddition of Activated Isocyanides with Azomethine Imines

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Uzoewulu, Chiamaka P.; Ohata, Jun: Translation of a Phosphine- and Azide-Based Reaction to Chemical Modification of Biomolecules in Ionic Liquid

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Issue 17/2022

Liu, Yue; Xu, Gaofei; Gao, Hongyin: [2,3]-Sigmatropic Rearrangement of Arylhydroxylamines: Rapid Access to ortho-Sulfonylated Anilines

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Hemmer, James R.; Berrocal, José Augusto: A Perspective on the Force-Induced Heterolytic Bond Cleavage in Triarylmethane Mechanophores

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Liu, Xingchen; Wang, Jixin; Li, Jie: Versatile OPiv-Supported Organozinc Reagents for Transition-Metal-Catalyzed Cross-Couplings

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Issue 16/2022

Zhou, Gang; Shen, Xiao: Visible-Light-Induced Organocatalyzed [2+1] Cyclization of Alkynes and (Trifluoroacetyl)silanes

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Feng, Tian; Wang, Siyi; Qiu, Youai: Electrochemical C–H Functionalization of Cyclic Amines

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Zhang, Peng; Feng, Jia; Liu, Ren-rong: Enantioselective Synthesis of Axially Chiral Benzimidazoles ­Bearing a C–N axis via Pd-Catalyzed Buchwald–Hartwig ­Amination

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Issue 15/2022

Budwitz, Jessica E.; Newton, Christopher G.: Ring Forming Approaches to para-Quinones: Toward a General Diels–Alder Disconnection

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Zhukhovitskiy, Aleksandr V.; Ratushnyy, Maxim; Ditzler, Rachael A. J.: Advancing the Logic of Polymer Synthesis via Skeletal Rearrangements

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Issue 13/2022

Argade, Malaika D.; Riley, Andrew P.: Syntheses of Aristotelia Alkaloids: Reflections in the Chiral Pool

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Issue 12/2022

He, Zhi-Tao: Phosphorus(III)-Promoted 1,2-Boronate Migration and Application to Stereoselective gem-C,B-Glycosylation

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Chaturvedi, Jagriti; Haldar, Chabush; Chattopadhyay, Buddhadeb: Electrostatically Directed meta-Selective Borylation of Arenes

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Issue 11/2022

Cao, Yanwei; He, Lin: Synthesis of Carbonyl Compounds by Gold-Catalyzed Carbonylation Reactions

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Filippini, Dario; Silvi, Mattia: The Conceptual Development of a Conjunctive Olefination

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Issue 10/2022

Zuo, Linhong; Guo, Wusheng: Zwitterionic Metal Enolates or Equivalents: Generation and Capture

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Li, Yanbang; Kopcha, William P.; Rodriguez-Fortea, Antonio; Zhang, Jianyuan: Multicomponent Reactions Among Alkyl Isocyanides, sp Reactants, and sp² Carbon Cages

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Jagadeesh, Chenna; Mondal, Biplab; Saha, Jaideep: Development of an Aza-Piancatelli-Templated Reaction Manifold from 4-Aminocyclopentenones: Access to Complex Carbocyclic Assemblies

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Issue 09/2022

Yuen, On Ying; So, Chau Ming: Palladium-Catalyzed Site-Selective Arylation of α,β-Unsaturated Carbonyl Compounds through a Ligand-Controlled Strategy

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Shen, Chaoren; Dong, Kaiwu: Assembling Chiral Center of Heterocycles by Palladium-Catalyzed Asymmetric Hydrocarbonylation

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Issue 08/2022

Morrison, Christine M.; Golder, Matthew R.: Ring-Expansion Metathesis Polymerization Initiator Design for the Synthesis of Cyclic Polymers

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Zhang, Zhuan; Durand, Natacha; Soulé, Jean-François: How Rhodium(I)-Catalyzed Phosphorus(III)-Directed C–H Bond Functionalizations Can Improve the Catalytic Activities of Phosphines

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Yang, Xinkan; Tsui, Gavin Chit: New Avenues in Copper-Mediated Trifluoromethylation Reactions Using Fluoroform as the CF₃ Source

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Issue 07/2022

Wang, Jia-Le; Zhuo, Chun-Xiang: Catalytic Deoxygenative Cyclopropanation of 1,2-Dicarbonyl or Monocarbonyl Compounds via Molybdenum Catalysis

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Kim, Byungjun; Kim, Yongjae; Lee, Sarah Yunmi: Stereoselective Michael Additions of Arylacetic Acid Derivatives by Asymmetric Organocatalysis

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Issue 06/2022

Dhankhar, Jyoti; Čorić, Ilija: Introduction to Spatial Anion Control for Direct C–H Arylation

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Wu, Xiang: Access to Chiral 1-Aminoindene Derivatives by Asymmetric Brønsted Acid Catalysis

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Issue 05/2022

Nie, Xingliang; liao, Saihu: Radical Fluorosulfonylation: Accessing Alkenylsulfonyl Fluorides from Alkenes and Alkynes

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Ma, Bin; Xiao, Ming-Jun; Liu, Pi-Jin; An, Peng: Synthesis of Azepine- or Azocine-Embedded Hexabenzocoronene-Based Nanographenes

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Issue 04/2022

Liu, Xu-Teng; Wu, Yue; Zhang, Qing-Wei: Nickel-Catalyzed Asymmetric Synthesis of P-Stereogenic Vinyl Phosphines

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Issue 03/2022

Kim, Ahreum; Kwon, Yongseok: Catalytic Atroposelective Dynamic Kinetic Resolution of Substituted Indoles

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Issue 02/2022

Shatskiy, Andrey; Kärkäs, Markus D.: Photoredox-Enabled Decarboxylative Synthesis of Unnatural α-Amino Acids Open Access

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Issue 01/2022

Grabicki, Niklas; Dumele, Oliver: Confining the Inner Space of Strained Carbon Nanorings

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Zhang, Yao-Yao; Yang, Guan-Wen; Wu, Guang-Peng: Recent Progress in Synthesizing Polyethers by Use of Organocatalysts

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Issue 20/2021

Lu, Hai-Hua; Cao, Meng-Yue: Enantioselective Palladium-Catalyzed Decarboxylative Dearomative Asymmetric Allylic Alkylation of Benzofurans: Diversity-Oriented Synthesis of Flavaglines

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Issue 19/2021

Saal, Fridolin; Ravat, Prince: Imide-Functionalized Helical PAHs: A Step towards New Chiral Functional Materials

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Yang, L.; Xue, D.: Transition-Metal-Catalyzed Hydroxylation Reaction of Aryl Halide for the Synthesis of Phenols

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Issue 18/2021

Chong, Chuanke; Lu, Zhaoyong: Bioinspired Total Synthesis of Marine Anticancer Meroterpenoids Dysideanone B and Dysiherbol A and Structure Revision of Dysiherbol A

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Issue 17/2021

Jiang, Zhong-Tao; Zeng, Yaxin; Xia, Ying: Rhodium-Catalyzed Direct Allylation of Simple Arenes by Using Gem-Difluorinated Cyclopropanes as Allyl Surrogates

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Issue 16/2021

Zhu, Jiefeng; He, Chuan: Catalytic Enantioselective Synthesis of Silicon-Stereogenic Alkoxy­silanes and Siloxanes

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Li, Ke; Sun, Zhe: Recent Advances in Dimeric Cycloparaphenylenes as Nanotube Fragments

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Issue 15/2021

Escudero-Casao, Margarita; Licini, Giulia; Orlandi, Manuel: Cu(I)–Bis(phosphine) Dioxides as Catalysts for the Enantioselective α-Arylation of Carbonyl Compounds

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Shi, Lou; Shu, Wei: Nickel-Catalyzed Electronically Reversed Enantioselective Hydrocarbofunctionalizations of Acrylamides

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Russell, John E. A.; Neufeldt, Sharon R.: C–O-Selective Cross-Coupling of Chlorinated Phenol Derivatives

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Issue 14/2021

Orellana, Norberto V.; Taylor, Michael T.: Targeting Tryptophan for Tagging through Photoinduced Electron Transfer

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Zhang, Qian; Xiong, Tao; Zhang, Qian: Transition-Metal-Catalyzed Alkylation of Polyfluoroarenes through C–F Bond Cleavage

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Issue 13/2021

Wang, Meng; Zhong, Changxu; Lu, Ping: Enantioselective Functionalization of Prochiral Cyclobutanones and Cyclobutenones

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Issue 12/2021

Shukla, Rahul K.; Nair, Akshay M.; Volla, Chandra M. R.: Allenes: Versatile Building Blocks in Cobalt-Catalyzed C–H Activation FREE ACCESS

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Kattamuri, Padmanabha V.; West, Julian G.: Cooperative Hydrogen Atom Transfer: From Theory to Applications

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Issue 11/2021

Jiang, Wei-Tao; Xiao, Bin: Alkylcarbagermatranes Permit an Alkylation-Terminated Catellani Reaction

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Zhang, Tianyi; Ondrus, Alison E.: Structure, Bonding, and Photoaffinity Labeling Applications of Dialkyldiazirines Open Access

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Issue 10/2021

Si, Xu-Ge; Zhang, Zhi-Mao; Cai, Quan: Asymmetric Inverse-Electron-Demand Diels–Alder Reactions of 2-Pyrones by Lewis Acid Catalysis

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Wu, Xianqing; Shrestha, Mohini; Chen, Yifeng: Asymmetric Synthesis of α-Alkylated γ-Lactam via Nickel/8-Quinim-Catalyzed Reductive Alkyl-Carbamoylation of Unactivated Alkene

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Issue 09/2021

Jones, Margaret R.; Schley, Nathan D.: Ligand-Driven Advances in Iridium-Catalyzed sp³ C–H Borylation: 2,2′-Dipyridylarylmethane

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Kempel, Samuel J.; Hsu, Ting-Wei; Michaudel, Quentin: Stereoretentive Olefin Metathesis: A New Avenue for the Synthesis of All-cis Poly(p-phenylene vinylene)s and Stereo­defined Polyalkenamers

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Issue 08/2021

Wang, Kun; Xiao, Miao; Wang, Chao: Synthesis of Chiral Amines via Asymmetric Hydrogen Borrowing

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Xiao, Xiao; Wengryniuk, Sarah E.: Recent Advances in the Selective Oxidative Dearomatization of Phenols to o-Quinones and o-Quinols with Hypervalent Iodine Reagents

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Issue 07/2021

Becica, Joseph; Leitch, David C.: C–O Bond Activation as a Strategy in Palladium-Catalyzed Cross-Coupling

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Li, Qi; Seiple, Ian B.: Modular Synthesis of Streptogramin Antibiotics

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Issue 06/2021

Gembreska, Nathan R.; Vogel, Alexander K.; Ziegelmeyer, Elizabeth C.; Cheng, Eric; Wu, Fan; Roberts, Leo P.; Vesoulis, Megan M.; Li, Wei: Halonium Catalysis: An Underutilized and Underexplored Catalytic Concept in Olefin Functionalizations

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Cai, Yuan; Shi, Shi-Liang: ANIPE-Cu Catalyst Enables Highly Enantioselective Markovnikov Hydroboration of α-Olefins

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Issue 04/2021

Zak, Inbal L.; Gadekar, Santosh C.; Milo, Anat: Designing the Secondary Coordination Sphere in Small-Molecule Catalysis

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Mei, Liangyong; Gianetti, Thomas: Helical Carbenium Ion-Based Organic Photoredox Catalyst: A Versatile and Sustainable Option in Red-Light-Induced Reactions

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Issue 03/2021

Sharafi, Mona; Campbell, Joseph P.; Murphy, Kyle E.; Osadchey Brown, Reilly; Schneebeli, Severin T.: Chiral Auxiliaries for Stereoselective Electrophilic Aromatic Substitutions

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Senior, Aaron; Ball, Liam T.: Bismuth(V)-Mediated C–H Arylation of Phenols and Naphthols

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Issue 02/2021

Hopkinson, Matthew N.; Mavroskoufis, Andreas: Photo-NHC Catalysis: Accessing Ketone Photochemistry with Carboxylic Acid Derivatives

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Li, Sida; Cui, Xin; Wang, Yue; Wu, Lipeng: Catalyst Development in the Dehydrogenative Borylation of Alkenes for the Synthesis Vinylboronate Esters

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Issue 01/2021

Holst, Hannah M.; McGuire, Shelby B.; Race, Nicholas J.: Revisiting the ‘Phenonium Phenomenon’: Regiodivergent Opening of Nonsymmetrical Phenonium Ions with Halide Nucleophiles

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Li, Yan-Lin; Gu, Zheng-Yang; Xia, Ji-Bao: Transition-Metal-Catalyzed Intermolecular C–H Carbonylation toward Amides

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Issue 20/2020

Zhang, Gang: Embedding Heteroatoms and Adjacent Pentagons in Concave Molecules

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Zhou, Min; Tsien, Jet; Qin, Tian: Unsymmetrical Heterocycle Cross-Couplings Enabled by Sulfur(IV) Reagents

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Issue 19/2020

Jin, Youxiang; Wang, Chuan: Nickel-Catalyzed Asymmetric Cross-Electrophile Coupling Reactions

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Popov, Stasik; Shao, Brian; Bagdasarian, Alex L.; Wigman, Benjamin; Nelson, Hosea M.: C–H Functionalization Reactions of Phenyl and Vinyl Carbocations Paired with Weakly Coordinating Anions

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Zhang, Hua; Wang, Li: Metal-Free Catalytic Aromatic C–H Borylation

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Issue 18/2020

Wang, Fang; Zhu, Shenqqing; Chu, Lingling: Synergistic Catalysis for Stereodivergent Synthesis of trans- and cis-Skipped Dienes

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Durham, Austin C.; Wang, Yidong; Wang, Yi-Ming: Redox-Neutral Propargylic C–H Functionalization by Using Iron Catalysis

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Hu, Ren-Ming; Lai, Yi-Huan; Xu, Da-Zhen: Iron-Catalyzed Aerobic Oxidative Cross-Dehydrogenative C(sp³)–H/X–H (X = C, N, S) Coupling Reactions

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Issue 17/2020

Chardon, Aurélien; Osi, Arnaud; Mahaut, Damien; Saida, Ali Ben; Berionni, Guillaume: Non-planar Boron Lewis Acids Taking the Next Step: Development of Tunable Lewis Acids, Lewis Superacids and Bifunctional Catalysts

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Zhang, Wei-Song; Hu, Yan-Cheng; Chen, Qing-An: Isoprene: A Promising Coupling Partner in C–H Functionalizations

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Garratt, George R. A.; Pattison, Graham: Formation of Boron Enolates by Nucleophilic Substitution

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Issue 16/2020

Wills, Rachel D.; Adebomi, Victor T.; Raj, Monika: Peptide Cyclization at High Concentration

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Chen, Wen-Wen; Zhao, Baoguo: Decarboxylative Umpolung Synthesis of Amines from Carbonyl Compounds

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Zhang, Fen; Zhao, Yu-Ming: Divergent Total Syntheses of Six Ganoderma Meroterpenoids: A Bioinspired Two-Phase Strategy

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Issue 15/2020

Koehler, Stephen J.; Hu, Jinzhen; Elacqua, Elizabeth: Electronically Governed ROMP: Expanding Sequence Control for Donor–Acceptor Conjugated Polymers

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Anthony, David; Diao, Tianning: Asymmetric Reductive Dicarbofunctionalization of Alkenes via Nickel Catalysis

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Issue 14/2020

Doobary, Sayad; Lennox, Alastair J. J.: Alkene Vicinal Difluorination: From Fluorine Gas to More Favoured Conditions

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Jung, Sangmin; Kim, Seo Yeon; Yoon, Hyo Jae: Force-Induced Cycloaddition of Aziridine: Can We Force a New Route?

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Issue 13/2020

Zheng, Wei; Li, Cheng-Hui: New Organic Dyes from Phthalonitrile via Interesting Nucleophilic Reactions

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Lange, Markus; Zi, You; Vilotijevic, Ivan: Latent (Pro)Nucleophiles in Enantioselective Lewis Base Catalyzed Allylic Substitutions

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Issue 12/2020

Lv, Wen; Wang, Weiping: One-Photon Upconversion-Like Photolysis: A New Strategy to Achieve Long-Wavelength Light-Excitable Photolysis

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Kang, Qi-Kai; Lin, Yunzhi; Li, Yuntong; Shi, Hang: Transition-Metal-Catalyzed Amination of Aryl Fluorides FREE ACCESS

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Issue 11/2020

Kramer, Philipp; Manolikakes, Georg: Rapid Assembly of Molecular Complexity from Simple Enamides

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Chen, Guo-Shu; Lin, Xiao-Tong; Liu, Yun-Lin: 3-(2-Isocyanoethyl)indole: A Versatile Reagent for Polycyclic Spiroindoline Synthesis

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Issue 10/2020

Xu, Ke; Wang, Ziyuan; Zhu, Tingshun: N-Heterocyclic Carbene-Organocatalyzed Arene Formation: Application in Atroposelective Synthesis of Polysubstituted Benzenes

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Gupta, Richa; Jaiswal, Amit K.; Mandal, Dipendu; Young, Rowan D.: A Frustrated Lewis Pair Solution to a Frustrating Problem: Mono-Selective Functionalization of C–F Bonds in Di- and Trifluoromethyl Groups

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Issue 09/2020

Li, Juncheng; Zhao, Gaoyuan; Wang, Ting: Organic-Photoacid-Catalyzed Glycosylation FREE ACCESS

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Wu, Chenggui; Cheng, Hong-Gang; Zhou, Qianghui: Epoxides as Dual-Functionalized Alkylating Reagents in Catellani Reactions for the Assembly of Heterocycles

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Issue 08/2020

Lauder, Kate; Castagnolo, Daniele: Photo-Biocatalytic Cascades for the Synthesis of Volatile Sulfur Compounds and Chemical Building Blocks

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Yan, Wenhao; Paeth, Matthew; Zacate, Samson; Zeng, Xiaojun; Liu, Wei: Late-Stage Difluoromethylation of Aliphatic Carboxylic Acids with Copper Catalysis

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Issue 07/2020

Pang, Xiaobo; He, Rong-De; Shu, Xing-Zhong: Construction of C–C Bond via C–N and C–O Cleavage

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Walther, Patrick; Vogler, Charlotte; Naumann, Stefan: Ultrahigh-Molecular-Weight Poly(propylene oxide): Preparation and Perspectives

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Issue 05/2020

Cringoli, Maria C.; Bellotto, Ottavia; De Zorzi, Rita; Vargiu, Attilio V.; Marchesan, Silvia: Self-Assembling l-d-l-Tripeptides Dance the Twist

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Sukhorukov, Alexey Yu.: Umpolung of Enamines: An Overview on Strategies and Synthons

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Issue 04/2020

Long, Xianwen; Ding, Yiming; Wu, Hai; Deng, Jun: Total Synthesis of Asperchalasine A

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Au-Yeung, Ho Yu; Ng, Antony Wing Hung: Mechanical Interlocking of Macrocycles in Different Sequences

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Issue 03/2020

Bai, Zengbing; Wang, Huan: Backbone-Enabled Peptide Macrocyclization through Late-Stage Palladium-Catalyzed C–H Activation

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Hyster, Todd K.: Radical Biocatalysis: Using Non-Natural Single Electron Transfer Mechanisms to Access New Enzymatic Functions FREE ACCESS

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Issue 02/2020

Pan, Ming-Lun; Wu, Yao-Ting: Synthesis of Biphenylenes and Their π-Extended Derivatives

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Short, Melanie A.; Blackburn, J. Miles; Roizen, Jennifer L.: Modifying Positional Selectivity in C–H Functionalization Reactions with Nitrogen-Centered Radicals: Generalizable Approaches to 1,6-Hydrogen-Atom Transfer Processes

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Babu, Kaki Raveendra; He, Xin; Xu, Silong: Lewis Base Catalysis Based on Homoconjugate Addition: Rearrangement of Electron-Deficient Cyclopropanes and Their Derivatives

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Issue 01/2020

Pawlicki, Miłosz: Multiple Coordination in Porphyrinoid Hybrid: Changing the Delocalization within the Extended π-System

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Zhang, Ye; Zhang, Lei; Qi, Xiangbing: Total Synthesis of (–)-Alstofolinine A: Selected Furan Oxidation/ Cyclization Cascade

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Issue 20/2019

Zhang, Lei; Hu, Mengjie; Peng, Bo: [3,3]- and [5,5]-Sigmatropic Rearrangements of Aryl Sulfoxides Using An ‘Assembly/Deprotonation’ Technology

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Du, Ke; Sue, Andrew C.-H.: The Trouble with Five: New Synthetic Strategies toward C₅-Symmetric Pillar[5]arenes and Beyond

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Issue 19/2019

Wu, Jia-Hong; Pan, Jianke; Wang, Tianli: Dipeptide-Based Phosphonium Salt Catalysis: Application to Enantioselective Synthesis of Fused Tri- and Tetrasubstituted Aziridines

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Shi, Yongjia; Gao, Qian; Xu, Senmiao: Iridium-Catalyzed Asymmetric C–H Borylation Enabled by Chiral Bidentate Boryl Ligands

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Issue 18/2019

Zhu, Rong: Emerging Catalyst Control in Cobalt-Catalyzed Oxidative Hydrofunctionalization Reactions

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Lardy, Samuel W.; Schmidt, Valerie A.: Regioselective Radical Alkene Amination Strategies by Using Phosphite-Mediated Deoxygenation

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Thiyagarajan, Subramanian; Gunanathan, Chidambaram: Ruthenium-Catalyzed Direct Cross-Coupling of Secondary Alcohols to β-Disubstituted Ketones FREE ACCESS

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Issue 17/2019

Empel, Claire; Koenigs, Rene M.: Sustainable Carbene Transfer Reactions with Iron and Light

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Boehlich, G. Jacob; Schützenmeister, Nina: β-Selective One-Pot Synthesis of Acyl-C-Glycosides via Corey–Seebach Umpolung Reaction

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Issue 16/2019

Music, Arif; Didier, Dorian: Organocerium: A New Contender for Halogen–Metal Exchanges

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Wang, Wang; Ding, Chao; Yin, Guoyin: Nickel-Catalyzed Migratory Arylboration of Nonactivated Alkenes

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Issue 15/2019

Barber, Ross W.; McFadden, Molly E.; Hu, Xiaoran; Robb, Maxwell J.: Mechanochemically Gated Photoswitching: Expanding the Scope of Polymer Mechanochromism

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Ukale, Dattatraya; Maity, Sajal; Hande, Madhuri; Lönnberg, Tuomas: Synthesis and Hybridization Properties of Covalently Mercurated and Palladated Oligonucleotides

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Issue 14/2019

Seath, Ciaran P.; Jui, Nathan T.: Intermolecular Reactions of Pyridyl Radicals with Olefins via Photoredox Catalysis

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Wei, Hongbo; Li, Yun: Quick Access to Pyridines through 6π-3-Azatriene Electrocyclization: Concise Total Synthesis of Suaveoline Alkaloids

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Issue 13/2019

Barthelemy, Anne-Laure; Tuccio, Béatrice; Magnier, Emmanuel; Dagousset, Guillaume: Intermolecular Trapping of Alkoxyl Radicals with Alkenes: A New Route to Ether Synthesis

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Claros, Miguel; Casitas, Alicia; Lloret-Fillol, Julio: Visible-Light Reductive Cyclization of Nonactivated Alkyl Chlorides

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Issue 12/2019

Tredwell, Matthew: Expanding the ¹⁸F-Radiochemical Space: Synthesis and Applications of 1,1-¹⁸F-Difluorinated Alkenes

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Vaitla, Janakiram; Bayer, Annette; Hopmann, Kathrin H.: Vinyl Sulfoxonium Ylide: A New Vinyl Carbenoid Transfer Reagent for the Synthesis of Heterocycles

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Issue 11/2019

Malcolmson, Steven J.; Li, Kangnan; Shao, Xinxin: 2-Azadienes as Enamine Umpolung Synthons for the Preparation of Chiral Amines

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Chun, Stephanie W.; Narayan, Alison R. H.: Biocatalytic Synthesis of α-Amino Ketones

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Issue 10/2019

Hu, Yue; Sun, Wei; Liu, Chao: Deoxygenative Transformation of Carbonyl and Carboxyl Compounds Using gem-Diborylalkanes

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Issue 09/2019

Juhl, Martin; Kim, Myungjo J.; Lee, Hee-Yoon; Baik, Mu-Hyun; Lee, Ji-Woong: Aldehyde Carboxylation: A Concise DFT Mechanistic Study and a Hypothetical Role of CO₂ in the Origin of Life

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Cruz, Carlos M.; Castro-Fernández, Silvia; Maçôas, Ermelinda; Millán, Alba; Campaña, Araceli G.: Combining Defects in a Single Nanographene: A Fully Helical Saddle Ribbon

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Wang, Xin; Zhu, Ming-Hui; Liu, Wen-Bo: Potassium Alkoxide/Disilane-Mediated Dehalogenative Deuteration

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Wang, Kuai; Kong, Wangqing: Enantioselective Reductive Diarylation of Alkenes by Ni-Catalyzed Domino Heck Cyclization/Cross Coupling

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Issue 08/2019

Rajkumar, Subramani; Wang, Jiawen; Yang, Xiaoyu: Asymmetric Transformations of α-Hydroxy Enamides Catalyzed by Chiral Brønsted Acids

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Habraken, Evi R. M.; Jupp, Andrew R.; Slootweg, J. Chris: Diazonium Salts as Nitrogen-Based Lewis Acids

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Issue 07/2019

Pallitsch, K.; Kalina, T.; Stanković, T.: Synthetic Phosphonic Acids as Potent Tools to Study Phosphonate Enzymology

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Ghiazza, Clément; Monnereau, Cyrille; Khrouz, Lhoussain; Médebielle, Maurice; Billard, Thierry; Tlili, Anis: New Avenues in Radical Trifluoromethylselenylation with ­Trifluoromethyl Tolueneselenosulfonate

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Issue 06/2019

Huang, Hai; Kang, Jun Yong: New Strategies for Activation of Phosphonates/Phosphates to Forge Functional Phosphorus Compounds

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Deng, Jiachen; Gui, Jinghan: Alkyne-Forming Furan Fragmentation: A General Method to Convert Furans into Alkynoic Acids

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Issue 05/2019

Kapoor, Mohit; Chand-Thakuri, Pratibha; Maxwell, Justin M.; Liu, Daniel; Zhou, Hanyang; Young, Michael C.: Carbon Dioxide-Driven Palladium-Catalyzed C–H Activation of Amines: A Unified Approach for the Arylation of Aliphatic and Aromatic Primary and Secondary Amines

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Dillon, Kearsley M.; Powell, Chadwick R.; Matson, John B.: Self-Immolative Prodrugs: Effective Tools for the Controlled Release of Sulfur Signaling Species

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Issue 03/2019

Haak, Edgar: Modern Annulation Strategies for the Synthesis of Cyclo[b]fused Indoles

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Lang, Jian; Wei, Ye: Difunctionalization of the Isocyano Group: Atom-Economic ­Synthesis of Pyrimidinediones

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Maity, Asim; Powers, David C.: Hypervalent Iodine Chemistry as a Platform for Aerobic Oxidation Catalysis

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Issue 02/2019

Bedi, Anjan; Gidron, Ori: Multiple Diels–Alder Transformations in Linear π-Conjugated Systems

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Yan, Zhongfei; Zhu, Chengjian; Xie, Jin: Manganese(I)-Catalyzed Selective Functionalization of Alkynes

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Issue 01/2019

Kanazawa, Junichiro; Uchiyama, Masanobu: Recent Advances in the Synthetic Chemistry of Bicyclo[1.1.1]pentane FREE ACCESS

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Barman, Milan K.; Waiba, Satyadeep; Maji, Biplab: Manganese-Catalyzed Direct Olefination via an Acceptorless Dehydrogenative Coupling of Methyl Heteroarenes with Primary Alcohols

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Issue 20/2018

Zhao, Wen-Tao; Gao, Fang; Zhao, Dongbing: Recent Progress in σ-Bond Cross-Exchange Reactions to Access Diverse Silacycles

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Li, Qing-Zhu; Liu, Yue; Leng, Hai-Jun; Li, Jun-Long: Asymmetric Construction of Halogenated Cyclic Quaternary Carbon Center through Enolate Activation of Aldehydes

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Issue 19/2018

Liu, Bin; Lim, Chern-Hooi; Miyake, Garret M.: Transition-Metal-Free, Visible-Light-Promoted C–S Cross-Coupling through Intermolecular Charge Transfer

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Bharadwaj, Saitanya K.; Bankar, Siddheshwar K.; Ramasastry, S. S. V.: Facile Access to Cyclopentadienes via Catalytic Intramolecular Palladium-Ene Reaction of 2,4-Pentadienyl Acetates

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Issue 18/2018

Johnson, Shea L.; Combee, Logan A.; Hilinski, Michael K.: Organocatalytic Atom-Transfer C(sp³)–H Oxidation

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Zhang, Liang; Wang, Yao: Uncovering Multifaceted Iodonium Ylides: Versatile Reactivity Enables Cyclization of Simple Arylamines

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Issue 17/2018

Ritschel, Benedikt; Lichtenberg, Crispin: Cationic Bismuth Compounds in Organic Synthesis and Catalysis: New Prospects for CH Activation

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Luo, Chaosheng; Bandar, Jeffrey S.: Synthesis of β-Phenethyl Ethers by Base-Catalyzed Alcohol Addition Reactions to Aryl Alkenes

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Issue 16/2018

Vandavasi, Jaya Kishore; Newman, Stephen G.: A High-Throughput Approach to Discovery: Heck-Type Reactivity with Aldehydes

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Chen, Gui; Yu, Yinghua; Huang, Xueliang: Palladium-Catalyzed Annulation via Acyl C–H Bond Activation

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Issue 15/2018

Zhao, Nan; Xie, Shengling; Huang, Hengjun; Xu, Jing: Total Synthesis of Astellatol: A Three-Decade Synthetic Puzzle

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Uttry, Alexander; van Gemmeren, Manuel: The Direct Pd-Catalyzed β-C(sp³)–H Activation of Carboxylic Acids

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Issue 14/2018

Guo, Rui; Zhang, Guozhu: Recent Advances in Intermolecular Hydroacylation of Alkenes with Aldehydes through Rhodium Catalysis

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Xu, Xiao-Long; Li, Zhi: Deciphering the Redox Chain Mechanism in the Catalytic Alkylation of Quinones

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Issue 13/2018

Van Humbeck, Jeffrey F.: Directing Methylene Oxidation towards Azaheterocycles by Transition-Metal and Organic Catalysis

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Cheng, Li-Jie; Brown, Alexander P. N.; Cordier, Christopher J.: From Propargylic Fluorinations to [1,3]-Rearrangements: Anion and Ligand Effects in Cu-Acetylide Chemistry

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Issue 12/2018

Topczewski, Joseph J.; Porter, Matthew R.: "It’s a (Kinetic) Trap!" – Selectively Differentiating Allylic Azide Isomers FREE ACCESS

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Gong, Honghong; Gu, Yu; Chen, Mao: Controlled/Living Radical Polymerization of Semifluorinated (Meth)acrylates

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Issue 11/2018

Guo, Chun; Kong, Dehui; Lei, Yi; Hili, Ryan: Expanding the Chemical Diversity of DNA

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Wang, Honggen; Zeng, Yao-Fu; Lv, Wen-Xin; Tan, Dong-Hang: Synthetic Transformations of Alkenyl MIDA Boronates toward the Efficient Construction of Organoborons

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Issue 10/2018

Du, Haiying; Dudognon, Yohan; Rodriguez, Jean; Constantieux, Thierry; Bugaut, Xavier: Weinreb β-Ketoamides in Enantioselective Organocatalysis: A Balance between Reactivity and Selectivity

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Štrukil, Vjekoslav: Mechanochemical Organic Synthesis: The Art of Making Chemistry Green

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Issue 09/2018

Lamb, Richard A.; Lessene, Guillaume; Hawkins, Bill C.: The Synthesis of (–)-Spiroleucettadine

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Narayanam, Maruthi Kumar; Ma, Gaoyuan; Champagne, Pier Alexandre; Houk, Kendall N.; Murphy, Jennifer M.: Nucleophilic ¹⁸F-Fluorination of Anilines via N-Arylsydnone Intermediates

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Issue 08/2018

Kalin, Alexander J.; Lee, Jongbok; Fang, Lei: Annulation Reactions for Conjugated Ladder-Type Oligomers

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Qin, Yang: Unconventional Conjugated Polymers Derived from a Common Set of trans-Enediyne Monomers

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Issue 07/2018

Okumura, Mikiko; Sarlah, David: Arenophile-Mediated Dearomative Functionalization Strategies

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Ma, Donghui; Wang, Zhang: Biomimetic Approaches: Synthesis of (±)-Homodimericin A

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Issue 06/2018

Mills, L. Reginald; Rousseaux, Sophie A. L.: Electrophilic Metal Homoenolates and Their Application in the Synthesis of Cyclopropylamines

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Pairault, Noel; Niemeyer, Jochen: Chiral Mechanically Interlocked Molecules – Applications of Rotaxanes, Catenanes and Molecular Knots in Stereoselective Chemosensing and Catalysis

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Issue 05/2018

Klapper, Martin; Arp, Johannes; Günther, Markus; Stallforth, Pierre: The Role of Bacterial Natural Products in Predator Defense

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Szamosvári, D.; Böttcher, T.: 4-Quinolone N-Oxides as Bacterial Weapons

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Issue 04/2018

Hu, Lu; Liu, Yahu A.; Liao, Xuebin: Recent Progress in Methylation of (Hetero)Arenes by Cross-Coupling or C–H Activation

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Liu, Binbin; Han, Wei: Iron-Catalyzed Wacker-Type Oxidation

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Issue 03/2018

Parry, Joseph B.; Fu, Niankai; Lin, Song: Electrocatalytic Difunctionalization of Olefins as a General Approach to the Synthesis of Vicinal Diamines

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Issue 02/2018

Choudhury, Joyanta; Semwal, Shrivats: Emergence of Stimuli-Controlled Switchable Bifunctional Catalysts FREE ACCESS

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Issue 01/2018

Soltani, Yashar; Wilkins, Lewis C.; Melen, Rebecca L.: A Comparative Assessment of Modern Cyclization Methods of Substituted Alkynyl Esters, Ethers, and Acids

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Dolewski, Ryan D.; Hilton, Michael C.; McNally, Andrew: 4-Selective Pyridine Functionalization Reactions via Heterocyclic Phosphonium Salts

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Issue 19/2017

Jacobse, Peter H.; Moret, Marc-Etienne; Klein Gebbink, Robertus J. M.; Swart, Ingmar: Tracking On-Surface Chemistry with Atomic Precision FREE ACCESS

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Hu, Jiadong; Yu, Xin; Xie, Weiqing: New Strategy for Forging Contiguous Quaternary Carbon Centers via H₂O₂-Mediated Ring Contraction

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Issue 18/2017

Hullaert, Jan; Denoo, Bram; Christiaens, Mien; Callebaut, Brenda; Winne, Johan M.: Heterocycles as Moderators of Allyl Cation Cycloaddition Reactivity

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Jeon, Sangbin; Park, Joonoh; Han, Sunkyu: Syntheses of Dimeric Securinega Alkaloids

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Issue 17/2017

Zhang, Ze-Xin; Chen, Si-Cong; Jiao, Lei: Asymmetric Total Synthesis of (+)-Minfiensine by an Asymmetric Cascade Cyclization Strategy

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Mitra, Nirmal K.; Merryman, Caroline P.; Merner, Bradley L.: Highly Strained para-Phenylene-Bridged Macrocycles from Unstrained 1,4-Diketo Macrocycles

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Issue 16/2017

Wan, Liqiang; Tian, Lan; Liu, Jie; Niu, Dawen: Iridium-Catalyzed Asymmetric Umpolung Allylation of N-Fluor­enyl Imines to Prepare 1,4-Disubstituted Homoallylic Amines

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Gurak, John A.; Engle, Keary M.: Regioselective Hydroamination Using a Directed Nucleopalladation/Protodepalladation Strategy

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Issue 15/2017

Feng, Quanyou; Zhong, Yongliang; Xie, Linghai; Tong, Rong: Recent Advances in Ring-Opening Polymerization of O-Carboxyanhydrides

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Hou, Zhong-Wei; Mao, Zhong-Yi; Xu, Hai-Chao: Recent Progress on the Synthesis of (Aza)indoles through Oxidative Alkyne Annulation Reactions

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Issue 14/2017

Hu, Long; Zhao, Junfeng: Ynamide: A New Coupling Reagent for Amide and Peptide Synthesis

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Lu, Dapeng; Cui, Shengsheng; Du, Pingwu: Large π-Extension of Carbon Nanorings by Incorporating Hexa-peri-hexabenzocoronenes

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Issue 13/2017

Ludwig, Jacob R.; Schindler, Corinna S.: Lewis Acid Catalyzed Carbonyl–Olefin Metathesis FREE ACCESS

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Zhu, Feng; Yang, Tianyi; Walczak, Maciej A.: Glycosyl Stille Cross-Coupling with Anomeric Nucleophiles – A General Solution to a Long-Standing Problem of Stereocontrolled Synthesis of C-Glycosides

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Issue 12/2017

Luan, Yi; Cong, Huan: Recent Synthetic Advances on π-Extended Carbon Nanohoops

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Mousa, Reem; Reddy, Post Sai; Metanis, Norman: Chemical Protein Synthesis through Selenocysteine Chemistry

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Issue 11/2017

Garcia-Bosch, Isaac: Copper-Catalyzed Oxidation of Alkanes under Mild Conditions

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Biswas, Promita; Paul, Subhasis; Guin, Joyram: Synthesis of 3,3-Dialkylated Oxindoles by Oxidative Radical 1,2-Alkylarylation of α,β-Unsaturated Amides

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Issue 10/2017

Sasaki, Kaname; Hashimoto, Yusuke: 2,6-Lactones as a New Entry in Stereoselective Glycosylations

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Heinze, Robert C.; Heretsch, Philipp: Synthesis of Secosterols as an Arena for C–H Functionalization and C–C Manipulation Tactics

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Issue 09/2017

Rout, Bhimsen; Bigliardi, Paul L.: Pattern-Generating Unimolecular Sensors: For Future Differential Sensing and Molecular Computing

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Mihai, Madalina T.; Phipps, Robert J.: Ion-Pair-Directed meta-Selective C–H Borylation of Aromatic Quaternary Ammonium Salts

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Issue 08/2017

Axelsson, Anton; Ta, Linda; Sundén, Henrik: Biomimetic Oxidative Carbene Catalysis: Enabling Aerial Oxygen as a Terminal Oxidant

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Pace, Vittorio; Castoldi, Laura; Monticelli, Serena; Rui, Marta; Collina, Simona: New Perspectives in Lithium Carbenoid Mediated Homologations

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Issue 07/2017

Zhang, Zhen; Ju, Tao; Ye, Jian-Heng; Yu, Da-Gang: CO₂ = CO + O: Redox-Neutral Lactamization and Lactonization of C–H Bonds with CO₂

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Spell, Mark L.; Deveaux, Kristina; Bresnahan, Caitlin G.; Ragains, Justin R.: O-Glycosylation Enabled by Remote Activation

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Issue 06/2017

Yang, Wenlong; Chalifoux, Wesley A.: Rapid π-Extension of Aromatics via Alkyne Benzannulations

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Grenning, Alexander J.: Simplifying Complex Scaffold Synthesis: Knoevenagel Adduct Allyl Anions as Easily Generated Multifunctional Reagents

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Issue 05/2017

Wang, Zi-Xuan; Bai, Xiao-Yan; Li, Bi-Jie: Recent Progress of Transition-Metal-Catalyzed Enantioselective Hydroalkynylation of Alkenes

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Moon, Patrick J.; Lundgren, Rylan J.: Copper-Mediated Oxidative α-Arylation of Carbonyl Compounds with Boronic Acid Derivatives

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Issue 04/2017

Cao, Xiaosong; Shi, Yi; Gao, Haifeng: A Novel Chain-Growth CuAAC Polymerization: One-pot Synthesis of Dendritic Hyperbranched Polymers with Well-Defined Structures

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Luo, Jie; Liu, Xiang; Zhao, Xiaodan: Development of Chalcogenide Catalysts towards Trifluoromethylthiolation

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Issue 03/2017

Stuart, David R.: Unsymmetrical Diaryliodonium Salts as Aryne Synthons: Renaissance of a C–H Deprotonative Approach to Arynes

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Carrow, Brad P.; Chen, Liye: Tri(1-adamantyl)phosphine: Exceptional Catalytic Effects Enabled by the Synergy of Chemical Stability, Donicity, and Polarizability

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Issue 02/2017

Ji, Xinjian; Zhang, Qi: Using Radical SAM Chemistry to Access Nucleoside-Containing Compounds

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Huang, Wenhao; Cheng, Xu: Hantzsch Esters as Multifunctional Reagents in Visible-Light Photoredox Catalysis

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Issue 01/2017

George, David T.; Kuenstner, Eric J.; Pronin, Sergey V.: Synthesis of Emindole SB

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Lefebvre, Quentin: Toward Sustainable Trifluoromethylation Reactions: Sodium Triflinate under the Spotlight

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Issue 20/2016

Ambler, Brett R.; Yang, Ming-Hsiu; Altman, Ryan A.: Metal-Catalyzed Decarboxylative Fluoroalkylation Reactions

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Liu, Yidong; Qin, Wenling; Yan, Hailong: Efficient Enrichment of Chiral β-Sulfonyl Ketones through Asymmetric β-Elimination

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Issue 19/2016

Huy, Peter H.; Hauch, Tanja; Filbrich, Isabel: Lewis Base Catalyzed Nucleophilic Substitutions of Alcohols

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Richmond, Edward; Moran, Joseph: Harnessing Complex Mixtures for Catalyst Discovery

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Issue 18/2016

Mei, Guang-Jian; Shi, Feng: Design and Application of 3-Alkyl-2-vinylindoles in Brønsted Acid Catalyzed Reactions

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Kim, Junghoon; Cho, Seung Hwan: Recent Developments in the Direct Methylation of Electron-­Deficient N-Heteroarenes

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Issue 17/2016

Zheng, Yan-Long; Luan, Yu-Xin; Ye, Mengchun: Recent Progress in Base Metal Catalyzed (Transfer) Hydrogenative Couplings of Carbonyls with π-Unsaturated Compounds

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Hasegawa, Masashi; Inoue, Ryota; Mazaki, Yasuhiro: Facile Synthesis of Thiacalix[n]thiophene Derivatives

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Issue 16/2016

Hao, Jing; Elkassih, Sussana; Siegwart, Daniel J.: Progress towards the Synthesis of Amino Polyesters via Ring-Opening Polymerization (ROP) of Functional Lactones

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Hindenberg, Philip; Romero-Nieto, Carlos: Phosphaphenalenes: An Evolution of the Phosphorus Heterocycles

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Issue 15/2016

Zhou, Hao; Shen, Mei-Hua; Xu, Hua-Dong: Evolution of the Aza-Diels–Alder Reaction of 2H-Azirines

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Satpathi, Bishnupada; Ramasastry, S. S. V.: Enantioselective Organocatalytic Intramolecular Morita–Baylis–Hillman Reaction of Some Unusual Substrates

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Issue 14/2016

Griffiths, Brendan M.; Burl, Jessica D.; Wang, Xiang: Bioinspired Discovery of Chemical Reactions and Biological Probes

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Bisht, Ranjana; Chattopadhyay, Buddhadeb: ortho- and meta-Selective C–H Activation and Borylation of Aromatic Aldehydes via in situ Generated Imines

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Issue 13/2016

Legacy, Christopher J.; Emmert, Marion H.: C_α–H Oxidations of Amines to Amides: Expanding Mechanistic Understanding and Amine Scope through Catalyst Development FREE ACCESS

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Tsakos, Michail; Jacobsen, Kristian M.; Yu, Wanwan; Villadsen, Nikolaj L.; Poulsen, Thomas B.: The Rakicidin Family of Anticancer Natural Products – Synthetic Strategies towards a New Class of Hypoxia-Selective Cytotoxins

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Issue 12/2016

Mendoza, Abraham; Colas, Kilian; Suárez-Pantiga, Samuel; Götz, Daniel C. G.; Johansson, Magnus J.: Chemical Innovation through Ligand Total Synthesis

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Drosos, Nikolaos; Ozkal, Erhan; Morandi, Bill: Catalytic Selective Deoxygenation of Polyols Using the B(C₆F₅)₃/Silane System

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Issue 11/2016

Pathak, Rakesh K.; Dhar, Shanta: Combined Chemo-Anti-Inflammatory Prodrugs and Nanoparticles

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Ravat, Prince; Šolomek, Tomáš; Ribar, Peter; Juríček, Michal: Biradicaloid with a Twist: Lowering the Singlet–Triplet Gap

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Issue 10/2016

Ting, Chi P.; Maimone, Thomas J.: The Total Synthesis of Hyperforin

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Liu, Liu; Wang, Qing; Zhu, Ranran; Huang, Jianhui: A Massé Shot: Transition-Metal-Catalyzed Selective meta-C–H Functionalization (ortho-Metallation and para-Bromination Relay)

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Issue 09/2016

Chen, Min; Yang, Bangpei; Chen, Changle: Redox Control in Olefin Polymerization and Copolymerization

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Yu, Yuanyuan; Li, Guang; Zu, Liansuo: The Development of Aza-Pinacol and Aza-Semipinacol Rearrangements for the Synthesis of Nitrogen-Containing Molecules

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Issue 08/2016

Beuerle, Florian; Klotzbach, Stefanie; Dhara, Ayan: Let’s Sort It Out: Self-Sorting of Covalent Organic Cage Compounds

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Ren, Rongguo; Zhu, Chen: Radical-Mediated Ring-Opening Functionalization of Cyclobutanols: A Shortcut to γ-Substituted Ketones

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Issue 07/2016

Larsson, Johanna; Demory, Emilien; Devaraj, Karthik; Sollert, Carina; Pilarski, Lukasz T.: Selective Activation of Arylboronate or Aryne Reactivity as a Versatile Postfunctionalization Strategy

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Nalbandian, Christopher J.; Hecht, David E.; Gustafson, Jeffrey L.: The Preorganization of Atropisomers to Increase Target Selectivity

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Issue 06/2016

Maza, Johnathan C.; Jacobs, Taylor H.; Uthappa, Diya M.; Young, Douglas D.: Employing Unnatural Amino Acids in the Preparation of Biooconjugates

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Uyeda, Christopher; Steiman, Talia J.; Pal, Sudipta: Catalytically Active Nickel–Nickel Bonds Using Redox-Active Ligands

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Issue 05/2016

Kuhnert, Maren; Diederich, Wibke E.: Structure-Based Drug Design in Medicinal Chemistry: The Devil is in the Detail

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Wei, Yu; Zeng, Xiaoming: Catalytic Strategies toward Selective Hydrogenation of Aromatic Ketones and Phenols: Facile Synthesis of Cyclohexyl Ketones

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Issue 04/2016

Song, Hayoung; Kim, Youngsuk; Park, Junbeom; Kim, Kimoon; Lee, Eunsung: Activation of Small Molecules at N-Heterocyclic Carbene Centers

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Mu, Yucheng; Zhu, Chendan; Shi, Zhuangzhi: Memory of Chirality (MOC) in Intramolecular sp³ C–H Amination

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Zhou, Bo; Li, Long; Ye, Long-Wu: Recent Progress in the Metal-Free or Nonnoble-Metal-Catalyzed Oxidation of Alkynes by Using Pyridine N-Oxides as External Oxidants

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Issue 03/2016

Lee, Katarzyna N.; Lee, Johnny W.; Ngai, Ming-Yu: Synthesis of Trifluoromethoxylated (Hetero)Arenes via OCF₃ Migration

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Stepherson, Jacob R.; Ayala, Caitlan E.; Dange, Nitin S.; Kartika, Rendy: Nucleophilic Capture of Unsymmetrical Oxyallyl Cations with Indoles under Mild Brønsted Acid Catalysis

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Turlik, Aneta; Chen, Yifeng; Newhouse, Timothy R.: Dehydrogenation Adjacent to Carbonyls Using Palladium–Allyl Intermediates

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Issue 02/2016

Bunrit, Anon; Dahlstrand, Christian; Srifa, Pemikar; Olsson, Sandra K.; Huang, Genping; Biswas, Srijit; Himo, Fahmi; Samec, Joseph S. M.: Nucleophilic Substitution of the Hydroxyl Group in Stereogenic Alcohols with Chirality Transfer

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von Delius, Max: Small Is (also) Beautiful: Dynamic Covalent Self-Assembly of Cryptates

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Lemercier, Bérénice C.; Pierce, Joshua G.: Thiohydroximic Acids: Versatile Reagents for Organic Synthesis

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Issue 20/2015

Esguerra, Kenneth Virgel N.; Lumb, Jean-Philip: Adapting Melanogenesis to a Regioselective C–H Functionalization of Phenols

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Keohane, Colleen E.; Steele, Andrew D.; Wuest, William M.: The Rhizosphere Microbiome: A Playground for Natural Product Chemists

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Li, Jundong; Zhao, Huaibo; Zhang, Yandong: Recent Progress in the Synthesis of 5-Unsubstituted Pyrrolidines via [3+2] Cycloadditions

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Issue 19/2015

Lichtenecker, Roman J.; Schörghuber, Julia; Bisaccia, Marilena: Synthesis of Metabolic Amino acid Precursors: Tools for Selective Isotope Labeling in Cell-Based Protein Overexpression

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Amir, Roey J.: Enzyme-Responsive PEG–Dendron Hybrids as a Platform for Smart Nanocarriers

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Fantoni, N.; Lauria, T.; Kellett, A.: Genome Engineering with Synthetic Copper Nucleases Open Access

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Šekutor, Marina: A Multidisciplinary Approach to the Study of Adamantyl Aminoguanidines – A New Class of Potentially Bioactive Compounds

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Issue 18/2015

Lewis, Chad A.; Moschitto, Matthew J.; Vaccarello, David N.: Allylic Oxide Regio-Resolution as a Tool for the Synthesis and Transfer of Carbasugars

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Shigehisa, Hiroki: Functional Group Tolerant Markovnikov-Selective Hydrofunctionalization of Unactivated Olefins Using a Cobalt Complex as Catalyst

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Pepper, Henry P.; George, Jonathan H.: The Biosynthesis and Biomimetic Synthesis of Merochlorins A and B

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Issue 17/2015

Huang, Yangjie; Huang, Ronglu; Weng, Zhiqiang: Transition-Metal-Mediated Synthesis of Trifluoroethyl Aryl Ethers

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Chen, Jianhui; Cao, Minyi; Cheng, Biao; Lu, Zhan: Catalytic Asymmetric Hydrosilylation of 1,1-Disubstituted Alkenes

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Issue 16/2015

Yoo, Eun Jeong: Azomethine Ylide: An Isolable 1,5-Dipole for Affecting [5+2] Cy­cloaddition Reactions

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Qiu, Dachuan; Shi, Jiarong; Li, Yang: Domino Aryne Precursor: A Step beyond the Boundary of Traditional Aryne Chemistry

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Issue 15/2015

Wang, Yuanhao; Lei, Xiaoqiang; Tang, Yefeng: Rhodium-Azavinylcarbene: A Versatile Synthon-Enabling Divergent Synthesis of Nitrogen Heterocycles

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Ure, Andrew D.; McDonald, Aidan R.: Nucleophilic Reactivity of a Metal-Bound Superoxide Ligand

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Issue 14/2015

Bencivenni, Giorgio: Organocatalytic Strategies for the Synthesis of Axially Chiral Compounds

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Zhao, Peng; Beaudry, Christopher M.: Total Synthesis of (+)-Cavicularin: The Pyrone Diels–Alder Reaction in Enantioselective Cyclophane Synthesis

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Issue 13/2015

Gupta, Anil K.; Hull, Kami L.: Synthesis of 1,2-Diamines via Hydroamination Reactions

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Issue 12/2015

Zhu, Liangyu; Tong, Rongbiao: Structural Revision of Uprolide G Acetate: Effective Interplay between NMR Data Analysis and Chemical Synthesis

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Issue 10/2015

Davis, Owen A.; Bull, James A.: Recent Advances in the Synthesis of 2-Substituted Oxetanes

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Issue 09/2015

Fyfe, James W. B.; Watson, Allan J. B.: Strategies towards Chemoselective Suzuki–Miyaura Cross-Coupling

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Zhang, Qing-Wei; An, Kun; He, Wei: Catalytic Synthesis of π-Conjugated Silole through Si–C (sp³) Bond Activation

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Issue 08/2015

Wang, Chao; Han, Jian; Zhao, Yingsheng: Recent Development in N-Auxilixary-Assisted Intramolecular Amination for Amine Substrates

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Coffey, Keith E.; Murphy, Graham K.: Dichlorination of α-Diazo-β-dicarbonyls Using (Dichloroiodo)benzene

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Issue 07/2015

Khan, Ajmal; Zhang, Yong Jian: Palladium-Catalyzed Asymmetric Decarboxylative Cycloaddition of Vinylethylene Carbonates with Electrophiles: Construction of Quaternary Stereocenters

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Molitor, Sebastian; Gessner, Viktoria H.: Lithium Chloride Carbenoids in Bond Activation Reactions

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Issue 06/2015

Giri, Ramesh; Thapa, Surendra: Copper-Catalyzed Cross-Couplings of Organometallic Reagents with and without Assistance from PN Ligands

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Nishikata, Takashi; Ishikawa, Shingo: Challenges in the Substitution of Terminal C–C Double Bonds with Tertiary Alkyl groups

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Issue 05/2015

Porel, Mintu; Brown, Joseph S.; Alabi, Christopher A.: Sequence-Defined Oligothioetheramides

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Hugelshofer, Cedric L.; Magauer, Thomas: Strategies for the Synthesis of Antifeedant Leucosceptroid Natural Products

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Issue 04/2015

Saloranta, Tiina; Leino, Reko: Unprotected Carbohydrates as Starting Material in Chemical Synthesis: Not Just a Challenge but an Opportunity

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Gollner, Andreas: The Frequent Application of Multicomponent and Cycloaddition Reactions for the Synthesis of Potent MDM2-p53 Inhibitors

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Beaud, Rodolphe; Tomakinian, Terry; Denizot, Natacha; Pouilhès, Annie; Kouklovsky, Cyrille; Vincent, Guillaume: The Quest for an Oxidative Coupling of Phenols and Indoles towards Benzofuroindolines: A Two-Stage Approach

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Issue 03/2015

Joshi, Tanmaya; Gasser, Gilles: Towards Tris(diimine)–Ruthenium(II) and Bis(quinoline)–Re(I)(CO)₃ Complexes as Photoactivated Anticancer Drug Candidates

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Samarasinghe, Kusal T. G.; Ahn, Young-Hoon: Synthesizing Clickable Glutathione by Glutathione Synthetase Mutant for Detecting Protein Glutathionylation

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Issue 02/2015

Thakur, Kavita; Sharma, Ritika; Sharma, Upendra: Olefins as Unprecedented Feedstock for the Synthesis of Valuable Heterocycles: Regioselectivity Remains an Issue

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Issue 01/2015

Glas, Adrian; Grossmann, Tom N.: Constraining Peptide Conformations with the Help of Ring-Closing Metathesis FREE ACCESS

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Issue 20/2014

Yayla, Hatice G.; Knowles, Robert R.: Proton-Coupled Electron Transfer in Organic Synthesis: Novel Homolytic Bond Activations and Catalytic Asymmetric Reactions with Free Radicals

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Lin, Chin-Yin; Chein, Rong-Jie: Lithiation of a Silyl Ether: Anionic Si→C Alkyl Migration

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Issue 19/2014

Lerch, Stephanie; Unkel, Lisa-Natascha; Wienefeld, Patrick; Brasholz, Malte: Ground- and Excited-State Quinones: Perspectives in Organocatalysis and Visible-Light Photocatalysis

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Nelson, Keegan G.; Larsen, Catharine H.: Condensation Versus Hydroamination for the Direct, Catalytic Synthesis of Tetrasubstituted Propargylamines

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Issue 18/2014

Biafora, Agostino; Patureau, Frederic W.: Perspective on Ruthenium–Copper-Mediated Dehydrogenative C–N Bond Formation

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Taniguchi, Tsuyoshi; Hirose, Daisuke; Hashimoto, Takuma: A New Method for the Synthesis of 1,4-Diols: C(sp³)–H Hydroxylation Induced by Iron-Catalyzed Redox Hydration of Alkenes

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Issue 17/2014

Aïssa, Christophe: Stereoselectivity of Metal-Catalyzed Cyclizations of 1,6-Dienes

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Tseng, Kuei-Nin T.; Szymczak, Nathaniel K.: Dehydrogenative Oxidation of Primary Amines to Nitriles

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Issue 16/2014

McDonald, Stacey L.; Wang, Qiu: α-Amination of Phosphonates: A Direct Synthesis of α-Amino Phosphonic Acids and Their Derivatives

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Yates, Lisa M.; Marmelstein, Alan M.; Fiedler, Dorothea: Synthetic Pyrophosphorylation Methods and Their Use in Chemical Biology

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Issue 15/2014

Fuse, Shinichiro; Mifune, Yuto; Tanabe, Nobutake; Takahashi, Takashi: Microflow Technology: Another Solution for the Site-Selective Modification of Multifunctionalized Molecules

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Yang, Yang; Dai, Mingji: Total Syntheses of Lyconadins: Finding Efficiency and Diversity

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Issue 14/2014

Zhang, Qi; Chen, Kai; Shi, Bing-Feng: Recent Progress in the Synthesis of Functionalized β-Lactams through Transition-Metal-Catalyzed C(sp³)–H Amidation

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Weaver, Jimmie D.: Hydrodefluorination of Perfluoroarenes Meets Visible Light Photocatalysis

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Issue 13/2014

Li, Xuexiang; Shao, Xiangfeng: Synthesis of Heterasumanene

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Xu, Liang; Li, Pengfei: Differentiated Di- and Polyboron Compounds: Synthesis and Application in Successive Suzuki–Miyaura Coupling

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Issue 12/2014

Hennecke, Ulrich; Wilking, Michael: Desymmetrization as a Strategy in Asymmetric Halocyclization Reactions

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Trovitch, Ryan J.: Comparing Well-Defined Manganese, Iron, Cobalt, and Nickel Ketone Hydrosilylation Catalysts

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Issue 11/2014

He, Chi; Zhu, Chenlong; Ding, Hanfeng: Synthetic Strategies toward the Indoxamycin Family

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Jessen, Henning Jacob; Capolicchio, Samanta; Pavlovic, Igor; Thakor, Divyeshsinh Takhtasinh: Diphosphoinositol Polyphosphates: Polar Stars in Cell Signaling

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Issue 10/2014

Lam, Hiu Yung; Li, Xuechen: Serine/Threonine Ligation in Cyclizing Peptides

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Payne, James T.; Lewis, Jared C.: Upgrading Nature’s Tools: Expression Enhancement and Preparative Utility of the Halogenase RebH

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Issue 09/2014

Nicewicz, David A.; Hamilton, David S.: Organic Photoredox Catalysis as a General Strategy for Anti-Markovnikov Alkene Hydrofunctionalization

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Mankad, Neal P.: Non-Precious Metal Catalysts for C–H Borylation Enabled by Metal–Metal Cooperativity

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Issue 08/2014

Mo, Zhenbo; Deng, Liang: Post-Functionalization: A Useful Method for the Synthesis of Donor-Func­tionalized N-Heterocyclic Carbene–Transition-Metal Catalysts

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Rout, Bhimsen; Motiei, Leila; Margulies, David: Combinatorial Fluorescent Molecular Sensors: The Road to Differential Sensing at the Molecular Level

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Issue 07/2014

Breder, Alexander: Oxidative Allylic Amination Reactions of Unactivated Olefins – At the Frontiers of Palladium and Selenium Catalysis

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Zhuang, Zhe; Liao, Wei-Wei: Metal-Free-Catalyzed Intramolecular Carbocyanation of Activated Alkenes: New Entry To Access Functionalized Nitriles Containing Quaternary Carbon Centers

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Issue 06/2014

Cook, Silas P.: Artemisinin: A Case Study in the Evolution of Synthetic Strategy

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Rasik, Christopher M.; Brown, M. Kevin: Intermolecular Ketene–Alkene [2+2] Cycloadditions: The Significance of ­Lewis Acid Promoted Variants

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Issue 05/2014

Maity, Soham; Naveen, Togati; Sharma, Upendra; Maiti, Debabrata: Efficient and Stereoselective Nitration of Olefins with AgNO₂ and TEMPO

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Bhunia, Anup; Biju, Akkattu T.: Employing Arynes in Transition-Metal-Free, N-Heterocycle- Initiated Multicomponent Reactions

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Issue 04/2014

Wu, Hao; Liu, Ren-Rong; Jia, Yi-Xia: Asymmetric Friedel–Crafts Alkylation Reaction in the Construction of Trifluoromethylated All-Carbon Quaternary Stereocenters

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Tao, Hai-Yan; Wang, Chun-Jiang: A Facile Access to Piperidine Derivatives via Copper(I)-Catalyzed 1,3-Dipolar [6+3] Cycloadditions of Azomethine Ylides with Fulvenes

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Issue 03/2014

Zhao, Wanxiang; Sun, Jianwei: New Strategies for Medium- and Large-Ring Lactone Synthesis

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Baryal, Kedar N.; Zhu, Jianglong: Stereoselective Synthesis of S-Linked 2-Deoxy Sugars

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Issue 02/2014

Tadano, Shinji; Ishikawa, Hayato: Synthesis of Tryptophan-Based Dimeric Diketopiperazine Alkaloids Using Bioinspired Reactions

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Tripathi, Chandra Bhushan; Mukherjee, Santanu: Catalytic Enantioselective Halocyclizations beyond Lactones: Emerging Routes to Enantioenriched Nitrogenous Heterocycles

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Issue 01/2014

Yin, Jun; Gao, Shuanhu: Total Synthesis of (+)-Fusarisetin A: A Biomimetic Approach FREE ACCESS

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Palmer, Leoni I.; Read de Alaniz, Javier: Lewis Acid Catalyzed Rearrangement of Furylcarbinols: The Aza- and Oxa-Piancatelli Cascade Reaction FREE ACCESS

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Issue 20/2013

Wang, Yong; Su, Xiang; Chen, Chao: One-Pot Synthesis of Multiply Substituted Quinoline and Quinazoline Derivatives via [2+2+2] Cascade Annulation with Diaryliodonium Salts

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Jungbauer, Stefan H.; Schindler, Severin; Kniep, Florian; Walter, Sebastian M.; Rout, Laxmidhar; Huber, Stefan M.: Multidentate Halogen-Bond Donors as Lewis Acidic Activators or Catalysts in Halide Abstraction Reactions

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Issue 19/2013

Liu, Guodu; Xu, Guangqing; Luo, Renshi; Tang, Wenjun: Search for Ideal P-Chiral Phosphorus Ligands for Practical Asymmetric Hydrogenation and Asymmetric Suzuki–Miyaura Coupling

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Rao, Yu: Pd-Catalyzed sp² C–H Hydroxylation with TFA/TFAA via Weak Coordina­tions

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Issue 18/2013

Jerković, Igor: Volatile Benzene Derivatives as Honey Biomarkers

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Balmond, Edward I.; Galan, M. Carmen; McGarrigle, Eoghan M.: Recent Developments in the Application of Organocatalysis to Glycosylations

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Lunde, Sindre Å.; Sydnes, Magne O.: One-Pot Procedures for the Formation of Secondary Aryl Amines from Nitro Aryls

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Jirgensons, Aigars; Grigorjeva, Liene; Maleckis, Ansis; Klimovica, Kristine: Unsaturated Amino Alcohols via Cyclization of Allylic Bistrichloroacetimidates

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Issue 17/2013

Martin, Sara E. S.; Watson, Donald A.: Silyl-Heck Reactions for the Preparation of Unsaturated Organosilanes

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Tang, Yongxing; Yang, Hongwei; Cheng, Guangbin: Recent Advanced Strategies for Extending the Nitrogen Chain in the Synthesis of High Nitrogen Compounds

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Issue 16/2013

Sui, Xianwei; Zhu, Rui; Gu, Zhenhua: Palladium-Catalyzed Chemoselective Catellani ortho-Arylation Reactions and Their Applications in Natural Products Synthesis

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Issue 15/2013

Songis, Olivier; Cazin, Catherine S. J.: [Pd(NHC)(PR₃)] Complexes: Versatile Tools for Tandem Dehydrogenation–Hydrogenation Processes

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Liu, Xiaowu; Wu, Xiaoxing: Development and Challenges in the Copper-Catalyzed Trifluoromethylation of Alkenes

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Issue 14/2013

Li, Ya-Min; Yang, Shang-Dong: New Strategies for Transition-Metal-Catalyzed C–P Bond Formation

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Zhang, Lei; Huang, Zheng: Iron-Catalyzed Alkene Hydroboration with Pinacolborane

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Issue 13/2013

Banerjee, Ranjan; Brown, Douglas R.; Weerapana, Eranthie: Recent Developments in the Synthesis of Bioactive 2,4,6-Trisubstituted 1,3,5-Triazines

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Wang, Congyang: Manganese-Mediated C–C Bond Formation via C–H Activation: From Stoichiometry to Catalysis

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Issue 12/2013

Mourad, Asmaa Kamal; Czekelius, Constantin: Enantioselective Functionalization of Terminal Alkynes by Gold Catalysis

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Nakamura, Hitomi; Balskus, Emily P.: Using Chemical Knowledge to Uncover New Biological Function: Discovery of the Cylindrocyclophane Biosynthetic Pathway

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Issue 11/2013

Liu, Hui; Jiang, Xuefeng: Mechanistic Insight to the Reaction Pathway of Aerobic Oxidative C–C Bond Cleavage of α-Hydroxy Ketones

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Stępień, Marcin: Recent Advances in the Synthesis of Bowl-Shaped Aromatic Compounds

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Issue 10/2013

Lu, Shenci; Poh, Si Bei; Siau, Woon-Yew; Zhao, Yu: Kinetic Resolution of 3-Hydroxy-3-Substituted Oxindoles through NHC-Catalyzed Oxidative Esterification

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Issue 09/2013

Schwarzer, Darius D.; Gritsch, Philipp J.; Gaich, Tanja: How to ‘Cope’ with the Prenylation of the Indole C4 Position

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Wang, Xiaoming; Li, Houhua; Lei, Xiaoguang: Challenges and Strategies to the Total Syntheses of Fawcettimine-Type and Serratinine-Type Lycopodium Alkaloids

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Issue 08/2013

Gillingham, Dennis; Tishinov, Kiril: Synthesis of Nucleic Acid Polymers with Non-Canonical Nucleobases

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Plunkett, Kyle N.: What About the Five-Membered Ring? Cyclopenta-fused Polycyclic Aromatic Hydrocarbons as a Building Block for Functional Materials

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Issue 07/2013

Paradies, Jan: Frustrated Lewis Pair Catalyzed Hydrogenations

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Mastalerz, Michael: Modular Synthesis of Shape-Persistent Organic Cage Compounds: Molecular Precursors for a New Class of Permanent Porous Materials

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Issue 06/2013

Nagorny, Pavel; Sun, Zhankui; Winschel, Grace A.: Chiral Phosphoric Acid Catalyzed Stereoselective Spiroketalizations

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Issue 05/2013

Greenhalgh, Mark D.; Thomas, Stephen P.: Iron-Catalyzed Hydromagnesiation of Olefins

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Issue 04/2013

Schomaker, Jennifer M.; Grigg, R. David: Activating Group Recycling: A Fresh Approach to Arene Functionalization

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Cai, Qian; Zhou, Fengtao: Development and Challenges in Copper-Catalyzed Asymmetric Ullmann-Type Coupling Reactions

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Issue 03/2013

Lalic, Gojko; Rucker, Richard P.: Copper-Catalyzed Electrophilic Amination of Organoboron Compounds

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Streuff, Jan: An Update on Catalytic Strategies for the Synthesis of α-Hydroxyketones

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Issue 02/2013

Gao, Lu; Zhang, Yuebao; Song, Zhenlei: Exploration of Versatile Geminal Bis(silane) Chemistry

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Wang, Chengming; Huang, Yong: Expanding Structural Diversity; Removable and Manipulable Directing Groups for C–H Activation

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Issue 01/2013

Dong, Guangbin: Ketone-Based Transition-Metal-Catalyzed Carbon–Carbon and Carbon– Hydrogen Bond Activation: Exploratory Studies FREE ACCESS

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Rohlmann, Renate; García Mancheño, Olga: Metal-Free Oxidative C(sp³)–H Bond Couplings as Valuable Synthetic Tools for C–C Bond Formations FREE ACCESS

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Issue 20/2012

Hyatt, I. F. Dempsey; Meza-Aviña, Maria Elena; Croatt, Mitchell P.: Alkynes and Azides: Not Just for Click Reactions

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Kim, Haejin; Rhee, Young Ho: A Perspective on the Stereodefined N,O-Acetals: Synthesis and Potential Applications

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Issue 19/2012

Phun, Lien H.; Aponte-Guzman, Joel; France, Stefan: Acid-Catalyzed Ring-Opening Isomerizations of Cyclopropenes

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Wang, Yan; Hoen, Rob; Hong, Ran: Development of a Nonenzymatic Kinetic Resolution of α-Allenic Alcohols

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Issue 18/2012

Vallakati, Ravikrishna; May, Jeremy A.: Biomimetic Syntheses of the Flindersial Alkaloids

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Issue 17/2012

Zhang, Sheng; Bao, Ming: Synthesis of Naphthylamines and Anthrylamines via η³-Benzylpalladium Intermediates

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Issue 16/2012

Yang, Jiong: Recent Developments in Nitrone Chemistry: Some Novel Transformations

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Issue 15/2012

Devaraj, Neal K.: Advancing Tetrazine Bioorthogonal Reactions through the Development of New Synthetic Tools

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Issue 14/2012

Mazet, Clément: Challenges and Achievements in the Transition-Metal-Catalyzed Asymmetric α-Arylation of Aldehydes

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Issue 13/2012

Maity, Soumitra; Zheng, Nan: A Photo Touch on Amines: New Synthetic Adventures of Nitrogen Radical Cations

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Issue 12/2012

Watson, Mary P.; Maity, Prantik: Controlling Enantioselectivity in Additions to Cyclic Oxocarbenium Ions via Transition-Metal Catalysis

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Issue 11/2012

Han, Changho; Kim, Eun Hoo; Colby, David A.: Cleaving Carbon–Carbon Bonds by the Release of Trifluoroacetate to Remodel Molecules and Assemble Fluorinated Structures

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Issue 10/2012

Ingleson, Michael J.: A Perspective on Direct Electrophilic Arene Borylation

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Issue 09/2012

Jenkins, David M.: Atom-Economical C₂ + N₁ Aziridination: Progress towards Catalytic Intermolecular Reactions Using Alkenes and Aryl Azides

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Issue 08/2012

Joshi-Pangu, Amruta; Biscoe, Mark R.: The Use of Tertiary Alkylmagnesium Nucleophiles in Ni-Catalyzed Cross-Coupling Reactions

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Issue 07/2012

Xu, Tao; Liu, Guosheng: Silver-Catalyzed Fluorination Reactions

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Issue 06/2012

Samanta, Rajarshi; Antonchick, Andrey P.: Metal-Free Oxidative C-H Bond Amination at Ambient Temperature

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Issue 05/2012

Proutiere, Fabien; Schoenebeck, Franziska: Orthogonal Selectivities under Pd(0) Catalysis with Solvent Polarity: An Interplay of Computational and Experimental Studies

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Issue 04/2012

Sisto, Thomas J.; Jasti, Ramesh: Overcoming Molecular Strain: Synthesis of [7]Cycloparaphenylene

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Issue 03/2012

Tan, Kian L.; Sun, Xixi; Worthy, Amanda D.: Scaffolding Catalysis: Expanding the Repertoire of Bifunctional Catalysts

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Issue 02/2012

Jones, Kevin M.; Klussmann, Martin: Oxidative Coupling of Tertiary Amines: Scope, Mechanism and Challenges

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Issue 01/2012

Zhou, Jianrong (Steve): Recent Developments in Asymmetric Coupling of Enolates

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Issue 20/2011

Xu, Zhenghu; Wang, Hong: Asymmetric Inverse-Electron-Demand Hetero-Diels-Alder Reaction via Enamine-Metal Lewis Acid Bifunctional Catalysis

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Issue 19/2011

Taylor, Buck L. H.; Jarvo, Elizabeth R.: Construction of Enantioenriched Tertiary Stereogenic Centers by Nickel- and Palladium-Catalyzed Cross-Coupling Reactions of Alkyl Electrophiles

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Issue 18/2011

Bronner, Sarah M.; Goetz, Adam E.; Garg, Neil K.: Understanding and Modulating Indolyne Regioselectivities

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Chain, William J.: Synthetic Strategies toward the Guaiane Sesquiterpene Englerin A

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Issue 17/2011

Reisman, Sarah E.; Nani, Roger R.; Levin, Sergiy: Buchner and Beyond: Arene Cyclopropanation as Applied to Natural Product Total Synthesis

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Issue 16/2011

Ryan, Sarah; Candish, Lisa; Lupton, David W.: N-Heterocyclic Carbene (NHC)-Catalyzed All-Carbon [4+2] Cycloaddition-Decarboxylation

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Issue 15/2011

Herzon, Seth B.: Enantioselective Syntheses of (-)-Kinamycin F and (-)-Lomaiviticin Aglycon

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Issue 14/2011

Han, Wei; Ofial, Armin R.: No Detours: Palladium-Catalyzed Oxidative C-H/C-H Cross-Couplings of Heteroarenes

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Powner, Matthew W.; Sutherland, John D.; Szostak, Jack W.: The Origins of Nucleotides

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Issue 13/2011

Bao, Hongli; Qi, Xiangbing; Tambar, Uttam K.: Stereoselective [2,3]-Rearrangements of Amine N-Oxides

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Hazari, Nilay; Hruszkewycz, Damian P.; Wu, Jianguo: Pd(I)-Bridging Allyl Dimers: A New System for the Catalytic Functionalization of Carbon Dioxide

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Issue 12/2011

Osowska, Karolina; Miljanić, Ognjen Š.: Kinetic and Thermodynamic Self-Sorting in Synthetic Systems

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Ho, Chun-Yu; He, Lisi; Chan, Chun-Wa: NHC-NiH Reactions with Simple Olefins: Advances in Hydroalkenylation, Polymerization, and Ionic-Liquid Synthesis

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Issue 11/2011

Muthaiah, Senthilkumar; Hong, Soon Hyeok: Atom-Economical Synthesis of Cyclic Imides

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Issue 10/2011

Tan, Chong Kiat; Zhou, Ling; Yeung, Ying-Yeung: Organocatalytic Enantioselective Halolactonizations: Strategies of Halogen Activation

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Sheppard, Tom D.: Alternative Approaches to Enolate Chemistry

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Issue 09/2011

Yoshida, Jun-ichi; Saito, Kodai; Nokami, Toshiki; Nagaki, Aiichiro: Space Integration of Reactions: An Approach to Increase the Capability of Organic Synthesis

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Issue 08/2011

Bucher, Christoph; Gilmour, Ryan: Steering Glycosylation with the Carbon-Fluorine Bond

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Yoshikai, Naohiko: Cobalt-Catalyzed, Chelation-Assisted C-H Bond Functionalization

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Issue 06/2011

Luparia, Marco; Audisio, Davide; Maulide, Nuno: Palladium-Catalysed Synthesis of Stereodefined Cyclobutenes

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Wu, Tsun-Cheng; Wu, Yao-Ting: Metal-Catalyzed Cascade Reactions of Ethynyl-Substituted Naphthalenes: Synthesis of Polycyclic Arenes

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Issue 05/2011

De Simone, Filippo; Waser, Jérôme: Cyclization of Aminocyclopropanes in Indole Alkaloids Synthesis

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Issue 03/2011

Paquin, Jean-François: Synthesis of Monofluoroalkenes via the Activation of Allylic C-F Bonds: A Novel Route to β-Aminofluoroalkenes Using Pd-Catalyzed Allylic Amination Reactions of 3,3-Difluoropropenes

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Issue 01/2011

Lin, Sibo; Agapie, Theodor: Cross-Coupling Chemistry at Mononuclear and Dinuclear Nickel Complexes

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