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Synlett 2018; 29(16): 2087-2092
DOI: 10.1055/s-0037-1610025
DOI: 10.1055/s-0037-1610025
synpacts
Palladium-Catalyzed Annulation via Acyl C–H Bond Activation
We acknowledge financial support from NSFC (Grant No. 21402197, 21502190), NSF of Fujian (Grant No. 2015J05043, 2017J01031), Hundred-Talent Program and the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB20000000). G. C. also thanks Dongguan University of Technology for startup grants (G200906-47 and GC200109-17).Further Information
Publication History
Received: 06 April 2018
Accepted after revision: 26 April 2018
Publication Date:
12 June 2018 (online)
Abstract
Palladium-catalyzed annulation of ortho-bromobenzaldehydes with aryl diazoesters is achieved via a sequence of palladium carbene migratory insertion, acyl C–H bond activation and reductive elimination of a seven-membered palladacyclic intermediate. A variety of isocoumarin derivatives were furnished in a straightforward manner.
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For selected reviews, see:
For selected examples of cross-couplings involving palladium carbenes, see: