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DOI: 10.1055/a-1702-4732
Synthesis of Azepine- or Azocine-Embedded Hexabenzocoronene-Based Nanographenes
We are grateful for the financial support provided by the National Natural Science Foundation of China (21901226 and 22061046).
Abstract
Classical polycyclic aromatic hydrocarbons (PAHs) are a large group of π-conjugated planar structures. To explore more properties of PAHs, new structures have been designed, including some with nonplanar topologies and heteroatom-containing moieties. As important nanographene (NG) units, hexabenzocoronene (HBC) and its derivatives have been intensively researched. Many HBC-based nonplanar NGs have been developed, and heteroatom-doped HBC-based NGs have also been designed and synthesized. Here, we summarize some methods for the synthesis of HBC-based NGs containing a seven- or eight-membered ring, and we discuss our newly synthesized NGs containing embedded azepine or azocine moieties, obtained by a modified synthetic route and a conventional Müllen’s synthetic method, respectively.
Key words
nanographenes - Diels–Alder reaction - polycyclic aromatic hydrocarbons - hexabenzocoronenes - azepines - azocinesPublication History
Received: 08 November 2021
Accepted after revision: 22 November 2021
Accepted Manuscript online:
22 November 2021
Article published online:
20 December 2021
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