One-Pot Procedures for the Formation of Secondary Aryl Amines from Nitro Aryls

Sindre Å. Lunde; Magne O. Sydnes

doi:10.1055/s-0033-1339860

Synlett, Inhaltsverzeichnis

Synlett 2013; 24(18): 2340-2344
DOI: 10.1055/s-0033-1339860

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One-Pot Procedures for the Formation of Secondary Aryl Amines from Nitro Aryls

Sindre Å. Lunde

Department of Mathematics and Natural Science, Faculty of Science and Technology, University of Stavanger, 4036 Stavanger, Norway Fax: +4751831750 eMail: magne.o.sydnes@uis.no

,

Magne O. Sydnes*

Department of Mathematics and Natural Science, Faculty of Science and Technology, University of Stavanger, 4036 Stavanger, Norway Fax: +4751831750 eMail: magne.o.sydnes@uis.no

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Abstract

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Abstract

Strategies for the one-pot formation of secondary aryl amines from the corresponding nitro aryls by utilizing reductive amination procedures are discussed. The extension of this chemistry where a Suzuki–Miyaura cross-coupling is conducted between a boronic acid and bromonitrobenzene prior to the reductive amination in one-pot is also presented.

Key words

one pot - Suzuki–Miyaura cross-coupling - reductive monoalkylation - biaryl - secondary amine

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Referenzen

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