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Synlett 2020; 31(20): 1957-1961
DOI: 10.1055/s-0040-1706411
DOI: 10.1055/s-0040-1706411
synpacts
Embedding Heteroatoms and Adjacent Pentagons in Concave Molecules
This work was supported by the Jiangsu Specially Appointed Professor Plan.Further Information
Publication History
Received: 29 June 2020
Accepted after revision: 11 July 2020
Publication Date:
10 August 2020 (online)
Abstract
Bowl-shaped molecules, which can be viewed as fragments of fullerenes, have been extensively studied owing to their interesting fundamental properties derived from their unique geometry, and the possibilities for their further functionalization, with potential applications in the field of materials science. Most of the reported concave compounds are based on corannulene or sumanene, the simplest representative fullerene subunits possessing isolated pentagons. Syntheses of concave molecules bearing adjacent pentagons have rarely been reported. Inspired by the structure of N-heterotriangulene, the construction of bowl-shaped compounds containing two fused pentagons and a central nitrogen atom is discussed. Further surface extension of such concave molecules can result in the formation of boat-shaped compounds containing embedded double isolated nitrogen atoms.
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