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Synlett 2024; 35(13): 1465-1470
DOI: 10.1055/s-0042-1751514
DOI: 10.1055/s-0042-1751514
synpacts
Construction of Bibenzothiophenes through Oxidative C–H Cyclization with 1,3-Diynes
This work was supported by grants from the National Natural Science Foundation of China (22171188), the Natural Science Foundation of Sichuan Province (2022NSFSC0295) and the Fundamental Research Funds for the Central Universities.
Abstract
The development of concise and efficient methods to construct bithiophene derivatives is an appealing task in the fields of organic chemistry and organic functional materials. Herein, we summarize our recent efforts towards the development of catalytic oxidative C–H cyclization reactions of thiophenol derivatives with 1,3-diynes, which provides a straightforward and effective synthetic approach to both symmetrical and nonsymmetrical 3,3′-bibenzothiophenes. This work is expected to stimulate the application of catalytic oxidative C–H annulation of aromatics with 1,3-diynes for the exploitation of organic functional materials.
Key words
oxidative cyclization - C–H functionalization - bibenzothiophenes - 1,3-diynes - heptagonal imidesPublication History
Received: 07 September 2023
Accepted after revision: 21 September 2023
Article published online:
31 October 2023
© 2023. Thieme. All rights reserved
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