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Synlett 2014; 25(13): 1799-1802
DOI: 10.1055/s-0033-1339114
DOI: 10.1055/s-0033-1339114
synpacts
Differentiated Di- and Polyboron Compounds: Synthesis and Application in Successive Suzuki–Miyaura Coupling
Weitere Informationen
Publikationsverlauf
Received: 16. März 2014
Accepted after revision: 10. April 2014
Publikationsdatum:
23. Mai 2014 (online)


Abstract
Differentiated polyboron compounds have emerged as powerful building blocks for modular assembly of complex molecules through selective Suzuki–Miyaura coupling (SMC). Recent progress in this area is briefly reviewed. A novel methodology involving iridium-catalyzed C–H borylation and highly selective SMC toward synthesis and application of this type of building blocks is discussed.