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DOI: 10.1055/a-1679-7959
Recent Progress in Synthesizing Polyethers by Use of Organocatalysts
This work was supported by the Zhejiang Provincial Natural Science Foundation of China (R21B040004) and the National Natural Science Foundation of China (51973186 and 91956123).
Abstract
Aliphatic polyethers are one of the most widely used polymers, whose synthesis is largely dependent on metallic compounds. Recent development of organocatalysts may break the limits of this long-standing field and infuse vitality into polyether production. In this Synpacts article, the recent advances of organocatalysts for polyether production is introduced in aspects of catalytic performance and mechanism. Moreover, attentions are paid to the latest contributions of bifunctional organoboron catalysts which can be prepared with high yields from cost-effective raw materials in two facile reactions and show excellent performance in the polyether production with remarkable catalytic efficiency, controllability on molecular weight, and explicit polymerization mechanism. Based on these advances, it is envisioned that new discoveries using organocatalysts will continue in the foreseeable future.
1 Introduction
2 Challenges in Metallic Catalysts
3 Previous Advances in Organocatalysts
4 Recent Contributions of Bifunctional Organoboron Catalysts
5 Conclusion
Key words
organocatalysts - polyethers - ring-opening polymerization - epoxides - organoboron - mechanismPublication History
Received: 18 October 2021
Accepted after revision: 27 October 2021
Accepted Manuscript online:
27 October 2021
Article published online:
22 November 2021
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