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Synlett 2015; 26(07): 861-865
DOI: 10.1055/s-0034-1380000
DOI: 10.1055/s-0034-1380000
synpacts
Lithium Chloride Carbenoids in Bond Activation Reactions
Further Information
Publication History
Received: 09 December 2014
Accepted after revision: 12 January 2015
Publication Date:
10 February 2015 (online)
Abstract
The field of transition-metal-free bond activation reactions has grown rapidly over the past years. In this context, lithium carbenoids have received renewed interest because of their unique electronic properties and their ambiphilic character. Stabilization of these usually highly reactive and thermally labile compounds has allowed the isolation of species that are stable at room temperature and enabled the development of new applications. In this article, we highlight the latest advances in the stabilization of Li/Cl carbenoids and their use in bond-activation chemistry.
1 Introduction
2 Classical Carbenoid Chemistry
3 Isolation and Properties of Li/Cl Carbenoids
4 Reactivity towards Boranes: B–X Bond Activation Reactions
5 Reactivity towards Phosphines
6 Conclusions
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For examples for other long-lived Li/Hal carbenoids, see:
For other examples of carbenoids in boron chemistry, see: