Multicomponent Reactions Among Alkyl Isocyanides, sp Reactants, and sp2 Carbon Cages

Yanbang Li; William P. Kopcha; Antonio Rodriguez-Fortea; Jianyuan Zhang

doi:10.1055/a-1741-9000

Synlett, Table of Contents

Synlett 2022; 33(10): 907-912
DOI: 10.1055/a-1741-9000

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Multicomponent Reactions Among Alkyl Isocyanides, sp Reactants, and sp² Carbon Cages

Yanbang Li

^aDepartment of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 123 Bevier Rd, Piscataway, NJ 08854, USA

,

William P. Kopcha

^aDepartment of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 123 Bevier Rd, Piscataway, NJ 08854, USA

,

Antonio Rodriguez-Fortea∗

^bDepartament de Química Física i Inorgànica, Universitat Rovira i Virgili, Marcel·lí Domingo 1, 43007, Tarragona, Spain

,

Jianyuan Zhang∗

^aDepartment of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 123 Bevier Rd, Piscataway, NJ 08854, USA

› Author Affiliations

Abstract

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Abstract

We explored the reactivity and substrate scope of the reactions among an alkyl isocyanide, an sp-hybridized reactant (i.e. alkyne or allene), and a carbon cage, as a new approach to functionalize fullerenes and metallofullerenes. This account summarizes the key findings in our recent published work, and some original data for the reaction involving an isocyanide, allenes, and metallofullerene Lu₃N@C₈₀.

1 Introduction

2 Isocyanide-Induced Fullerene/EMF Reactions with Substituted Alkynes

3 Isocyanide-Induced Fullerene/EMF Reactions with Substituted Allenes

4 Conclusion

Key words

isocyanide - cluster motion - endohedral - fullerenes - multicomponent reaction

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References

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