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Synlett 2012(6): 809-813  
DOI: 10.1055/s-0031-1290531
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© Georg Thieme Verlag Stuttgart ˙ New York

Metal-Free Oxidative C-H Bond Amination at Ambient Temperature

Rajarshi Samanta, Andrey P. Antonchick*
Max-Planck-Institute of Molecular Physiology, Department of Chemical Biology, Otto-Hahn-Str. 11, 44227 Dortmund, Germany
Fax: +49(231)7552499; e-Mail: andrey.antonchick@mpi-dortmund.mpg.de;
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Publikationsverlauf

Received 28 November 2011
Publikationsdatum:
24. Februar 2012 (online)

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Abstract

Direct oxidative methods of C-H bond functionalization represent efficient straightforward approaches in formation of new bonds. Those transformations allow coupling of nonprefunctionalized building blocks and engaged growing attention from academic and industrial communities. Recent results on development of environmentally benign oxidative aminations of C-H bonds are highlighted.

Key words

arylation - catalysis - iodine - cross-coupling - amination

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