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Synlett 2019; 30(16): 1850-1854
DOI: 10.1055/s-0037-1610719
DOI: 10.1055/s-0037-1610719
synpacts
Nickel-Catalyzed Migratory Arylboration of Nonactivated Alkenes
This work was supported by the National Natural Science Foundation of China (No. 21702151, 21871211) and the Fundamental Research Funds for Central Universities.Further Information
Publication History
Received: 06 May 2019
Accepted after revision: 29 May 2019
Publication Date:
26 June 2019 (online)
◊ These authors contributed equally to this paper.
Abstract
An unprecedented nickel-catalyzed 1,n-arylboration (n >2) of terminal nonactivated alkenes has been developed. This reaction is the first example of a regioselective arylboration of terminal nonactivated alkenes and features high selectivity, wide functional-group tolerance, and operational simplicity. Remarkably, preliminary mechanistic studies indicated that an equilibrium of various nickel intermediates exists in this transformation, but bond formation is favored at the benzylic position.
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