Recent Development in N-Auxilixary-Assisted Intramolecular Amination for Amine Substrates

Chao Wang; Jian Han; Yingsheng Zhao

doi:10.1055/s-0034-1380167

Synlett, Inhaltsverzeichnis

Synlett 2015; 26(08): 997-1002
DOI: 10.1055/s-0034-1380167

synpacts

Recent Development in N-Auxilixary-Assisted Intramolecular Amination for Amine Substrates

Chao Wang

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. of China eMail: yszhao@suda.edu.cn

,

Jian Han

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. of China eMail: yszhao@suda.edu.cn

,

Yingsheng Zhao*

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. of China eMail: yszhao@suda.edu.cn

› Institutsangaben

Abstract

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Abstract

Direct coupling of N–H with C–H has aroused great attention in the last decades; during which the directing-group-assisted intramolecular C–N bond formation via transition metal has been achieved significant progress. Herein, we highlight the recent development in the directing-group-assisted intramolecular amination for amine substrates to build the important N-containing heterocyclic compounds.

1 Introduction

2 Triflamide-Promoted Intramolecular Amination

3 Picolinamide-Assisted Intramolecular Amination

4 Palladium-Catalyzed Intramolecular Amination under Assistance of Oxalyl Amide

5 Conclusion

Key words

amination - cyclization - transition metals - C–H activation - directing groups

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Referenzen

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