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Synlett 2018; 29(20): 2595-2600
DOI: 10.1055/s-0037-1610266
DOI: 10.1055/s-0037-1610266
synpacts
Recent Progress in σ-Bond Cross-Exchange Reactions to Access Diverse Silacycles
We are grateful for the financial support from the National Natural Science Foundation of China (21602115), 1000-Talent Youth Program (020/BF180181), the Natural Science Foundation of Tianjin (18JCYBJC20400), the Fundamental Research Funds for the Central Universities and Nankai University.Further Information
Publication History
Received: 15 June 2018
Accepted after revision: 10 August 2018
Publication Date:
30 August 2018 (online)
Abstract
The σ-bond cross-exchange reaction, which involves cleavage and subsequent exchange between different nonpolar σ-bonds, constitutes an attractive protocol for rapid access to organic skeletons with 100% atom economy. Herein, we give a brief summary of recent achievements in this approach for the synthesis of diverse silacycles, highlighting our recent advances in the first intermolecular σ-bond exchange between C–C bonds of cyclopropenones and C–Si bonds of (benzo)silacyclobutanes.
1 Introduction
2 σ-Bond Exchange-Reaction of Benzocyclobutanones to Silacycles
3 σ-Bond Exchange-Reaction of Ethyl Cyclopropylideneacetates to Silacycles
4 σ-Bond Exchange-Reaction of Cyclopropenones to Silacycles
5 Conclusion
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