Transition-Metal-Free, Visible-Light-Promoted C–S Cross-Coupling through Intermolecular Charge Transfer

Bin Liu; Chern-Hooi Lim; Garret M. Miyake

doi:10.1055/s-0037-1610230

Synlett, Inhaltsverzeichnis

Synlett 2018; 29(19): 2449-2455
DOI: 10.1055/s-0037-1610230

synpacts

Transition-Metal-Free, Visible-Light-Promoted C–S Cross-Coupling through Intermolecular Charge Transfer

Bin Liu

Department of Chemistry, Colorado State University, 301 West Pitkin Street, Fort Collins, CO 80523, USA eMail: garret.miyake@colostate.edu

,

Chern-Hooi Lim

Department of Chemistry, Colorado State University, 301 West Pitkin Street, Fort Collins, CO 80523, USA eMail: garret.miyake@colostate.edu

,

Garret M. Miyake *

Department of Chemistry, Colorado State University, 301 West Pitkin Street, Fort Collins, CO 80523, USA eMail: garret.miyake@colostate.edu

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Abstract

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Abstract

C–S cross-couplings are an important class of reactions applied across organic synthesis, materials science, and pharmaceuticals. Several different methodologies have been developed to achieve this significant transformation. However, currently available synthetic procedures significantly rely on transition metals. This article describes historical developments in the field of transition-metal-catalyzed C–S cross-coupling reactions, the development of a visible-light-driven and catalyst-free approach to C–S bond formation, and future outlooks.

Key words

C–S cross-coupling - transition-metal-free - photochemistry - charge transfer - late-stage functionalization - electron donor–acceptor complex

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Referenzen

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