Aminium-Radical-Mediated Intermolecular Hydroamination of Nonactivated Olefins

Si-Ming Jia; Yi-Hang Huang; Fei Wang

doi:10.1055/s-0042-1751390

Synlett, Inhaltsverzeichnis

Synlett 2023; 34(02): 93-100
DOI: 10.1055/s-0042-1751390

synpacts

Aminium-Radical-Mediated Intermolecular Hydroamination of Nonactivated Olefins

Si-Ming Jia

,

Yi-Hang Huang

,

Fei Wang ∗

Abstract

Alle Artikel dieser Rubrik

Dedicated to Professor Qi-Lin Zhou on the occasion of his 65^th birthday.

Abstract

Aminium radicals are attractive intermediates in synthetic chemistry that readily participate in a series of C–N bond-forming processes. Here, we briefly discuss strategies for generating aminium radicals from various precursors in the context of intermolecular alkene amination, and we highlight recent advances in aminium-radical-mediated hydroaminations of nonactivated olefins to directly approach alkylamines.

1 Introduction

2 Intermolecular Hydroamination of Nonactivated Alkenes with Alkylamines under Photoredox Catalysis

3 Intermolecular Hydroamination of Nonactivated Alkenes with Aliphatic Azides

4 Conclusions

Key words

aminium radicals - hydroamination - alkenes - alkylamines - aliphatic azides

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Referenzen

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