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Synlett 2023; 34(02): 93-100
DOI: 10.1055/s-0042-1751390
DOI: 10.1055/s-0042-1751390
synpacts
Aminium-Radical-Mediated Intermolecular Hydroamination of Nonactivated Olefins
We are grateful to the financial support from the National Natural Science Foundation of China (Grants 22101140, 22188101), the Fundamental Research Funds for the Central Universities (Grant 63223009), and Haihe Laboratory of Sustainable Chemical Transformations, Frontiers Science Center for New Organic Matter at Nankai University (Grant 63181206).
Dedicated to Professor Qi-Lin Zhou on the occasion of his 65th birthday.
Abstract
Aminium radicals are attractive intermediates in synthetic chemistry that readily participate in a series of C–N bond-forming processes. Here, we briefly discuss strategies for generating aminium radicals from various precursors in the context of intermolecular alkene amination, and we highlight recent advances in aminium-radical-mediated hydroaminations of nonactivated olefins to directly approach alkylamines.
1 Introduction
2 Intermolecular Hydroamination of Nonactivated Alkenes with Alkylamines under Photoredox Catalysis
3 Intermolecular Hydroamination of Nonactivated Alkenes with Aliphatic Azides
4 Conclusions
Publication History
Received: 05 October 2022
Accepted after revision: 27 October 2022
Article published online:
23 November 2022
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