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Synlett
DOI: 10.1055/a-2500-6758
DOI: 10.1055/a-2500-6758
synpacts
Synthesis of Silyl Heterocycles Using Transborylation
Abstract
Silicon has been proposed as a nonclassical bioisostere to carbon in a ‘silicon-switch’ approach, however, the synthesis of complex molecules containing silyl heterocycles is still a significant challenge in preparing ‘silicon-switch’ molecules. Transborylation, the σ-bond metathesis between two boron species, has been utilized for the synthesis of complex molecules, in an orthogonal approach to transition-metal catalysis. Here, the use of transborylation catalysis for the synthesis of structurally diverse silyl heterocycles is highlighted.
1 Introduction
2 Transborylation in Catalysis
3 Silyl Heterocycles
4 Synthesis of Silyl Heterocycles Using Transborylation
5 Conclusions and Outlook
Publication History
Received: 04 October 2024
Accepted after revision: 11 December 2024
Accepted Manuscript online:
11 December 2024
Article published online:
17 January 2025
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