Catalyst Development in the Dehydrogenative Borylation of Alkenes for the Synthesis Vinylboronate Esters
Sida Li
a
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou, 730000, P. R. of China Email: lipengwu@licp.cas.cn
b
University of Chinese Academy of Sciences, Beijing, 100049, P. R. of China
,
Xin Cui
a
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou, 730000, P. R. of China Email: lipengwu@licp.cas.cn
,
Yue Wang
a
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou, 730000, P. R. of China Email: lipengwu@licp.cas.cn
,
Lipeng Wu∗
a
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou, 730000, P. R. of China Email: lipengwu@licp.cas.cn
b
University of Chinese Academy of Sciences, Beijing, 100049, P. R. of China
› Author AffiliationsWe are grateful to the National Natural Science Foundation of China (21901247, 91845108, 21902167), the Natural Science Foundation of Jiangsu Province (BK20180246), and the Innovation and Entrepreneurship Talents Plan of Jiangsu Province for their generous financial support.
Catalytic dehydrogenative borylation of alkenes provides an efficient and straightforward method for the preparation of synthetically useful vinylboronate esters. Here, we present a summary of developments and recent advances in this area, classified according to the various reactants and catalyst systems.
1 Introduction
2 Catalytic Dehydrogenative Borylation of Alkenes by Using Boranes
3 Catalytic Dehydrogenative Borylation of Alkenes by Using Diboranes
4 Zirconium-Catalyzed H2–Acceptorless Dehydrogenative Borylation of Alkenes with Boranes
