Nickel-Catalyzed Asymmetric Cross-Electrophile Coupling Reactions

Youxiang Jin; Chuan Wang

doi:10.1055/s-0040-1707216

Synlett, Inhaltsverzeichnis

Synlett 2020; 31(19): 1843-1850
DOI: 10.1055/s-0040-1707216

synpacts

Nickel-Catalyzed Asymmetric Cross-Electrophile Coupling Reactions

Youxiang Jin

^aHefei National Laboratory for Physical Science at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. of China

,

Chuan Wang ∗

^aHefei National Laboratory for Physical Science at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. of China

^bCenter for Excellence in Molecular Synthesis of CAS, Hefei, Anhui 230026, P. R. of China eMail: chuanw@ustc.edu.cn

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Abstract

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Abstract

The merger of cross-electrophile coupling and asymmetric catalysis provides a novel approach to the preparation of optically active compounds. This method is often endowed with high step economy, mild conditions, and excellent tolerance of functional groups. Recent advances in the research field of nickel-catalyzed asymmetric cross-electrophile coupling reactions are highlighted in this concise Synpacts article.

1 Introduction

2 Asymmetric Cross-Electrophile Coupling Reactions between Organohalides

3 Asymmetric Electrophilic Ring-Opening Reactions

4 Asymmetric Electrophilic Difunctionalization of Alkenes

4.1 Two-Component Electrophilic Difunctionalization of Alkenes Involving Arylnickelation as an Enantiodetermining Step

4.2 Two-Component Electrophilic Difunctionalization of Alkenes Involving Carbamoylnickelation as an Enantiodetermining Step

4.3 Three-Component Electrophilic Difunctionalization of Alkenes

5 Asymmetric Electrophilic Functionalization of Carbonyl Compounds

6 Summary

Key words

nickel catalysis - asymmetric catalysis - reductive cross-coupling - umpolung - electrophiles

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Referenzen

References

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