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Synlett 2015; 26(18): 2479-2484
DOI: 10.1055/s-0035-1560171
DOI: 10.1055/s-0035-1560171
synpacts
Functional Group Tolerant Markovnikov-Selective Hydrofunctionalization of Unactivated Olefins Using a Cobalt Complex as Catalyst
Further Information
Publication History
Received: 11 June 2015
Accepted: 21 July 2015
Publication Date:
25 August 2015 (online)
Abstract
Recent developments in the Markovnikov-selective hydrofunctionalization of unactivated olefins are presented. Our group found that the use of a cobalt complex, an N-fluoropyridinium salt, and a siloxane facilitates hydrofunctionalization with excellent functional group tolerance. Mechanistically, this catalysis involves both a carbon radical and a carbocationic intermediate.
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