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Synlett 1992; 1992(11): 905-906
DOI: 10.1055/s-1992-21536
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Reactions of a Serine-derived Zinc/Copper Reagent with Tricarbonyl(cyclohexadienyl) Iron Salts: Synthesis of Protected Amino Acids

Michael J. Dunn* , Richard F. W. Jackson, G. Richard Stephenson
  • *Department of Chemistry, Bedson Building, The University, Newcastle upon Tyne, NE1 7RU, England
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Publication Date:
08 March 2002 (online)

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The serine derived zinc/copper reagent 1 reacts efficiently with tricarbonyl(η5-cyclohexadienyl)iron salts 3 to give the cyclohexadiene complexes 4, which can be converted to the metal-free protected amino acids by treatment with trimethylamine N-oxide.