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Synlett 1997; 1997(9): 1102-1104
DOI: 10.1055/s-1997-1546
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Unimolecular Chain Transfer (UMCT) Reactions of Silicon Hydrides: Controlling Relative Configuration in Hydrogen Transfer Reactions of Cyclic Radicals

Dennis P. Curran* , Jinyou Xu
  • *Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania, 15260, USA
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Publication History

Publication Date:
31 December 2000 (online)

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UMCT-controlled sequences of radical cyclization followed by 1,5-hydrogen transfer from diphenylsilanes or bis(trimethylsilyl)-silanes are introduced. The later silanes have improved reactivity.

unimolecular chain transfer (UMCT) reactions - radical cyclization - 1,5-hydrogen transfer - diphenylsilanes - bis(trimethylsilyl)silanes