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Synlett 1998; 1998(1): 99-101
DOI: 10.1055/s-1998-985344
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Stereoselective Synthesis of Allylic Sulfoximines from S-(Chloromethyl)-N-methyl-S-phenylsulfoximine and Alkenyl Cuprates

Stephan Boßhammer* , Hans-Joachim Gais
  • *Institut für Organische Chemie, Rheinisch-Westfälische Technische Hochschule Aachen, Professor-Pirlet-Straße 1, 52056 Aachen, Germany; Fax 02 41/8 88 81 27; E-mail: Gais@RWTH-Aachen.de
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Publication Date:
16 July 2007 (online)

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Enantio- and diastereometrically pure acyclic and cyclic allylic sulfoximines have been obtained by the reaction of (+)-(S)-S-(chloromethyl)-N-methyl-S-phenylsulfoximine with alkenyl cuprates of the type R2CuLi · LiCN.

allylic sulfoximines - alkenyl cuprates - α-halo sulfoximines