2.3 Single-Electron-Transfer Oxidation and Reduction Involving Metal Complexes other than Samarium

Abstract

Recent advances in the field of radical organic chemistry involving single-electron transfer (SET) are highlighted in this chapter. The focus is on processes between organic molecules and metal complexes that facilitate the creation of challenging covalent bonds. A selection of oxidation and reduction reactions is reported, with special attention paid to enantioselective reactions. Mechanistic discussions are also provided.

Schlüsselwörter

radical chemistry - organic synthesis - oxidation - reduction - single-electron transfer - metal complexes - enolate coupling - atom-transfer radical addition (ATRA) - C—H oxidation - amination - fluorination - enantioselective reactions - hydrofunctionalization - aryl coupling - phosphorylation

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