Synthesis, Inhaltsverzeichnis Synthesis 2022; 54(21): 4764-4772DOI: 10.1055/a-1683-9455 special topic Asymmetric C–H Functionalization Cationic Iridium/Chiral Bidentate Phosphoramidite Catalyzed Asymmetric Hydroarylation Tomohiko Shirai a Department of Materials Science and Engineering, National Institute of Technology, Kochi College Otsu, Monobe, Nangoku, Kochi 783-8508, Japan , Yasunori Yamamoto ∗ b Division of Chemical Process Engineering and Frontier Chemistry Center (FCC), Faculty of Engineering, Hokkaido University, Kita 13, Nishi 8, Kita-ku, Sapporo, Hokkaido 060-8628, Japan › Institutsangaben Artikel empfehlen Abstract Artikel einzeln kaufen Alle Artikel dieser Rubrik Abstract In this personal account, we summarize our investigations on the asymmetric direct addition of C(sp2)–H bonds to unsaturated bonds, such as C=O and C=C, using cationic iridium/chiral O-linked bidentate phosphoramidite (Me-BIPAM) and S-linked bidentate phosphoramidite (S-Me-BIPAM) catalyst systems. 1 Introduction 2 Highly Enantioselective Intramolecular Hydroarylation of α-Keto Amides 3 Highly Enantioselective Intermolecular Hydroarylation of Bicycloalkenes 4 Conclusion Key words Key wordsasymmetric synthesis - C–H functionalization - hydroarylation - iridium catalysts - chiral bidentate phosphoramidites Volltext Referenzen References 1a Kakiuchi F, Kochi T. 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