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Synthesis 2022; 54(12): 2799-2815
DOI: 10.1055/a-1767-3026
DOI: 10.1055/a-1767-3026
feature
Ferrocenephosphonates: Copper-Promoted Synthesis and Further Functionalization
This work was supported by the Université de Rennes 1, Centre National de la Recherche Scientifique (CNRS), the University of Carthage, the Ministère de l’Enseignement Supérieur et de la Recherche Scientifique (Tunisian Ministry of Higher Education and Scientific Research; grant for K. A.), and the Fonds Européen de Développement Régional (FEDER; European Regional Development Fund; D8 VENTURE Bruker AXS diffractometer).
Abstract
Ferrocenephosphonates make up an important class of organometallic derivatives with a wide range of useful applications in organic synthesis and coordination chemistry. Here, an approach to ferrocenephosphonates based on a copper-promoted Hirao coupling is reported. Further functionalizations based on regioselective deprotolithiation and both Negishi and Suzuki–Miyaura cross-coupling reactions are also described to reach original derivatives.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1767-3026.
- Supporting Information
- CIF File
Publication History
Received: 19 January 2022
Accepted after revision: 09 February 2022
Accepted Manuscript online:
09 February 2022
Article published online:
05 April 2022
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