Photochemical Activation of Sulfur Hexafluoride: A Tool for Fluorination and Pentafluorosulfanylation Reactions

David Rombach; Hans-Achim Wagenknecht

doi:10.1055/a-1877-5231

Synthesis, Inhaltsverzeichnis

CC BY-NC-ND 4.0 · Synthesis 2022; 54(22): 4883-4894
DOI: 10.1055/a-1877-5231

short review

Photochemical Activation of Sulfur Hexafluoride: A Tool for Fluorination and Pentafluorosulfanylation Reactions

David Rombach∗

^aLaboratory of Organic Chemistry, ETH Zürich, Vladimir-Prelog-Weg 3, 8093 Zürich, Switzerland

,

Hans-Achim Wagenknecht ∗

^bInstitute of Organic Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 6, 76131 Karlsruhe, Germany

› Institutsangaben

Abstract

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Abstract

The photoactivation of notoriously inert sulfur hexafluoride represents a challenge for photochemistry. This short review summarizes recently published efforts and the corresponding photochemical mechanisms for switching between the fluorination and pentafluorosulfanylation reactivity of organic substrates.

1 Introduction

2 Sulfur Hexafluoride (SF₆)

3 The Pentafluorosulfanyl (SF₅) Group

4 Photoredox Catalytic Activation of SF₆

5 Conclusions

Key words

photochemistry - photocatalysis - fluorination - electron transfer - light - sulfur hexafluoride - pentafluorosulfanylation

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Referenzen

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