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CC BY-NC-ND 4.0 · Synthesis 2022; 54(22): 4883-4894
DOI: 10.1055/a-1877-5231
DOI: 10.1055/a-1877-5231
short review
Photochemical Activation of Sulfur Hexafluoride: A Tool for Fluorination and Pentafluorosulfanylation Reactions
Financial support from the Deutsche Forschungsgemeinschaft (DFG) (Wa 1386/16-2), the Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung (SNF) (Swiss National Science Foundation) (CRSK-2_195863) and the Karlsruhe Institute of Technology (KIT) is gratefully acknowledged. D.R. thanks H.A.W., Prof. Dr. Antonio Togni and Prof. Dr. Erick M. Carreira for their continuous and generous support.
Abstract
The photoactivation of notoriously inert sulfur hexafluoride represents a challenge for photochemistry. This short review summarizes recently published efforts and the corresponding photochemical mechanisms for switching between the fluorination and pentafluorosulfanylation reactivity of organic substrates.
1 Introduction
2 Sulfur Hexafluoride (SF6)
3 The Pentafluorosulfanyl (SF5) Group
4 Photoredox Catalytic Activation of SF6
5 Conclusions
Key words
photochemistry - photocatalysis - fluorination - electron transfer - light - sulfur hexafluoride - pentafluorosulfanylationPublication History
Received: 21 April 2022
Accepted after revision: 08 June 2022
Accepted Manuscript online:
16 June 2022
Article published online:
25 August 2022
© 2022. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution-NonDerivative-NonCommercial-License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by-nc-nd/4.0/)
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