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Synthesis 2023; 55(07): 1079-1088
DOI: 10.1055/a-1979-8930
DOI: 10.1055/a-1979-8930
paper
Hydroamination of Carbodiimides Catalyzed by Lithium Triethylborohydride
Abstract
Commercially available lithium triethylborohydride (LiHBEt3) with a lower load of 0.5 mol% acts as an efficient catalyst for the hydroamination of various carbodiimides. It achieved good functional group tolerance under mild and solvent-free conditions. The possible mechanism and pathways of LiHBEt3 catalyzing the hydroamination of various carbodiimides are proposed.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1979-8930.
- Supporting Information
Publication History
Received: 16 September 2022
Accepted after revision: 16 November 2022
Accepted Manuscript online:
16 November 2022
Article published online:
08 December 2022
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