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Synlett 2023; 34(20): 2481-2485
DOI: 10.1055/a-2145-5986
DOI: 10.1055/a-2145-5986
cluster
Special Issue Dedicated to Prof. Hisashi Yamamoto
Copper-Catalyzed Construction of Amide Linkages via Coupling between Unactivated Acids and Amines
We sincerely thank Council of Scientific and Industrial Research, India (CSIR) for funding through the Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research (CSMCRI) Project Nos. MLP 0028, MLP 0067, and a SRF to A.R. We also thank the Science and Engineering Research Board (SERB) for funding through Grant no. CRG/2022/003868.
Dedicated to Professor Hisashi Yamamoto on the occasion of his 80th birthday
Abstract
Traditional amide linkage forming reactions by the coupling between an acid and an amine rely primarily on triggering the carboxylic acid counterpart with (over)stoichiometric activating agent(s) and generate unacceptable quantity of nondisposable waste, leading to poor atom economy. Herein, we report an efficient catalytic amide synthesis that proceeds through the in situ activation of the amine counterpart in the form of a reactive N-formyl amine species. The strategy gives an expedient access to an array of structurally varied amides, including dipeptides, from numerous genre of acids and amines without producing stoichiometric solid wastes.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2145-5986.
- Supporting Information
Publication History
Received: 13 June 2023
Accepted after revision: 31 July 2023
Accepted Manuscript online:
31 July 2023
Article published online:
14 September 2023
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For a review, see:
For an overview, see:
For selected examples, see:
For reviews on DMF as a reagent, see: