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Synthesis 2024; 56(02): 220-228
DOI: 10.1055/a-2155-3498
DOI: 10.1055/a-2155-3498
short review
Recent Developments on the Synthesis of Sulfoxides via Sulfenate Anions
This work was supported by the Walter Benjamin Program (500656103) of the Deutsche Forschungsgemeinschaft.
Abstract
Since the early 2000s, novel synthetic methods for the preparation of sulfoxides have emerged that involve sulfenate anions as sulfur nucleophiles. This short review showcases key advances in these sulfenate protocols, including catalytic enantioselective alkylation and arylation, and provides future directions for this research field.
1 Introduction
2 Precursors of Sulfenate Anions
3 Organocatalytic Enantioselective Alkylation of Sulfenate Anions
4 Palladium-Catalyzed Arylation of Sulfenate Anions
5 Coupling of Sulfenate Anions with Hypervalent Iodine Reagents
6 Conclusions and Outlook
Publication History
Received: 18 July 2023
Accepted after revision: 16 August 2023
Accepted Manuscript online:
16 August 2023
Article published online:
27 September 2023
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